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Limitation of the concentration of organic pollutants in sewage sludge for agricultural purposes: A case study in South Spain
Authors:I Aparicio  JL Santos  E Alonso
Institution:1. Aristotle University of Thessaloniki, Greece;2. University of Thessaly, Greece;3. National Technical University of Athens, Greece;1. Research Group of Analytical Chemistry and Life Sciences, Department of Analytical Chemistry, University of Granada, Campus of Fuentenueva, E-18071 Granada, Spain;2. Department of Chemistry, University of Tirana, St. Bulevardi \"Zogu I\", 1001 Tirana, Albania;1. Strategic Water Infrastructure Laboratory, School of Civil, Mining and Environmental Engineering, University of Wollongong, Wollongong, NSW 2522, Australia;2. State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, PR China;3. School of Applied Sciences, RMIT University, Bundoora 3083, Australia;4. Strategic Water Infrastructure Laboratory, School of Chemistry, University of Wollongong, Wollongong, NSW 2522, Australia
Abstract:In 2000, the EU published the third draft of a future sludge directive entitled “Working document on sludge” where limit values for some organic compounds, including di-(2-ethyhexyl)phthalate (DEHP), sum of nonylphenol (NP), nonyphenol mono-(NP1EO) and diethoxylates (NP2EO), seven polychlorinated biphenyl congeners (PCB), polycyclic aromatic hydrocarbons (PAH) and linear alkylbenzene sulphonates (LAS), are fixed. In the present work, the monitoring of these organic compounds in sludge samples from four wastewater treatment plants (WWTPs) is reported. All WWTPs use anaerobic biological stabilization of sludge. The highest concentration levels were found for LAS, NPE and DEHP, in this order, with, in general, anaerobically-digested dehydrated sludge and compost samples being the most contaminated samples. DEHP, NPE, LAS and PAH were found at concentration levels above the limit values fixed in the third draft of the future EU sludge directive in the 44%, 88%, 13% and 6% of the analyzed anaerobically-digested dehydrated sludge and compost samples.
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