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Elemental concentrations in aerosols at the Belgian coast versus seasons and air mass trajectories
Authors:Katleen Van Meel  Benjamin Horemans  Agnieszka Krata  László Bencs  Anna Jolanta Buczyñska  Alin C Dirtu  Anna Worobiec  René Van Grieken
Institution:(1) Environmental Analysis Group, Department of Chemistry, University of Antwerp, Universiteitsplein 1, 2610 Antwerp, Belgium;(2) Hungarian Academy of Sciences, Research Institute for Solid State Physics and Optics, P.O. Box 49, 1525 Budapest, Hungary;(3) Department of Inorganic and Analytical Chemistry, University “Al.I Cuza” of Iassy, 700506 Iasi, Romania
Abstract:Marine aerosols have extensively been monitored in the framework of a research project to investigate the inorganic and organic nutrient fluxes of the atmospheric nitrogen input into the North Sea. As a part of this project bulk analysis was also performed by energy dispersive X-ray fluorescence (EDXRF) on a total of 366 samples in order to provide detailed elemental composition. Samples have been clustered per campaign and differences were related to backward trajectories. Elements as Cl, Si, and S appeared to be the best tracers for coastal aerosols. Therefore they have been chosen to represent each campaign and to map the seasonal variations. It is clear that Cl is an excellent tracer for oceanic trajectories, while a less clear correlation between the soil dust components and the air mass trajectories is found.
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