Kinetic model for phenolic compound oxidation by Fenton's reagent |
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Authors: | De Heredia J B Torregrosa J Dominguez J R Peres J A |
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Affiliation: | Departamento de Ingenieria Quimica y Energetica, Universidad de Extremadura, Badajoz, Spain. jbelther@unex.es |
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Abstract: | A kinetic model is developed for the oxidation of phenolic compounds by Fenton's reagent. In the first stage a rigorous kinetic model is applied to calculate the different kinetic rate constants for the oxidation process of p-hydroxybenzoic acid. In a second phase a competitive method is applied to calculate these kinetic constants for another 10 phenolic compounds present in agroindustrial and pulp paper wastewaters. These 10 phenolic compounds were: beta-resorcylic acid, 3-(4-hydroxyphenyl)-propionic acid, ferulic acid, protocatechuic acid, caffeic acid, p-coumaric acid, vanillic acid, syringic acid, veratric acid and 3,4,5-trimethoxybenzoic acid. |
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