Synthesis of Segmented Polyurethane Based on Polymeric Soybean Oil Polyol and Poly (Ethylene Glycol) |
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Authors: | Elif Kele? Baki Hazer |
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Institution: | (1) Department of Chemistry, Faculty of Arts and Sciences, Zonguldak Karaelmas University, 67100 Zonguldak, Turkey; |
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Abstract: | Polyurethane (PUR) plastic sheets were prepared by reacting hydroxylated polymeric soybean oil (PSbOH) synthesized from autoxidized
soybean oil with polyethylene glycol (PEG) in the presence of isophorone diisocyanate (IPDI). FTIR technique was used to identify
of chemical reactions. These polyurethanes have different valuable properties, determined by their chemical composition. The
effect of stoichiometric balance (i.e., PSbOH/PEG-2000/IPDI weight ratio) on the final properties was evaluated. The polyurethane
plastic sheets with the PSbOH/PEG-2000/IPDI weight ratio 1.0/1.0/0.67 and 1.0/0.3/0.3 had excellent mechanical properties
indicating elongation at break more than 200%. Increase in IPDI and decrease in PEG weight ratio cause the higher stress–strain
value. The properties of the materials were measured by differential scanning calorimetry (DSC), thermo gravimetric analysis
(TGA), stress–strain measurements and FTIR technique. |
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Keywords: | |
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