A comparative analysis between temperature and pressure measurements for early detection of runaway initiation |
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Authors: | J. Bosch, F. Strozzi, T. J. Snee, J. A. Hare,J. M. Zaldí var, |
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Affiliation: | a Carlo Cattaneo University-LIUC, Quantitative Methods Institute, Castellanza, Italy b Health and Safety Laboratory, Process Safety Section, Harpur Hill, Buxton, Derbyshire SK17 9JN, UK c European Commission, Joint Research Centre, Institute for Environment and Sustainability, TP272, 21020, Ispra VA, Italy |
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Abstract: | In this work, we have analysed the use of pressure instead of temperature measurements for the early warning detection of runaway initiation. This is possible due to the fact that our runaway criterion, i.e. div>0, does not depend specifically on which state space variable we are using for divergence calculation. A series of runaway experiments, carried out in a 250 l pilot-scale reactor, has been used to compare the results. In accordance with previous analysis, we show that by using temperature, early detection of runaway initiation is achieved. Analogously to temperature, pressure may be also used for runaway detection. By comparing the different types of reactive systems analysed (vapour and gassy), it can be observed that temperature works better, in terms of earlier detection, than pressure but the differences are more pronounced for vapour than for gassy systems. |
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Keywords: | Runaway reactions Early warning detection Safety Dynamical systems |
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