Effects of anions on the kinetics and reactivity of nanoscale Pd/Fe in trichlorobenzene dechlorination |
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Authors: | Lim Teik-Thye Zhu Bao-Wei |
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Affiliation: | School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Republic of Singapore. cttlim@ntu.edu.sg |
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Abstract: | Influences of anionic co-solutes on dechlorination of 1,2,4-trichlorobenzene (124TCB) by the nanoscale Pd/Fe particles were investigated in batch experiments in the presence of an anionic solute such as nitrate, nitrite, perchlorate, phosphate, carbonate, silica, sulfate, sulfite, or sulfide. Based on the extent of inhibitory effects on the 124TCB dechlorination, the anions can be ranked in the order of: control≈sulfate≈silica
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