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电生羟基自由基降解有机染料的研究
引用本文:刘元兰,杜艳芳,陆嘉星.电生羟基自由基降解有机染料的研究[J].上海环境科学,2003,22(12):888-891.
作者姓名:刘元兰  杜艳芳  陆嘉星
作者单位:华东师范大学离子液体化学研究中心 上海200062 (刘元兰,杜艳芳),华东师范大学离子液体化学研究中心 上海200062(陆嘉星)
摘    要:以Pb/PbO2为工作电极,以CoSO4为催化剂,利用电生羟基自由基对中性红、罗丹明B、碱性品红等3种有机染料进行了降解。并且研究了电解电位、pH值、温度等因素对染料降解脱色的影响。结果表明.脱色率接近100%,COD去除率达90%以上。实验证明反应符合一级反应动力学模式,实验还测定了动力学参数。

关 键 词:电生羟基自由基  降解  有机染料  脱色  影响因素  动力学参数  废水处理

Study on Electro-Generated Hydroxyl Radical Using in Degradation of Dyes
Liu Yuanlan Du Yanfang Lu Jiaxing.Study on Electro-Generated Hydroxyl Radical Using in Degradation of Dyes[J].Shanghai Environmental Science,2003,22(12):888-891.
Authors:Liu Yuanlan Du Yanfang Lu Jiaxing
Abstract:Electro-generated hydroxyl radical was used to degrade neutral red, rhodamine B and alkaline fuch sine with Pb/PbO2 as electrode and CoSO4 as ca -talysis. The affected factors of electrolysis potential, pH value, temperature etc. in dyes'degrading and decolorizing have been studied. The results showed that the decolorizing rate was near 100% and COD removal rate was above 90%. The experiments proved that the reaction according with grade I reactive kinetic mode, and kinetic parameters were also determined.
Keywords:Electro-generated hydroxyl radical Organic dye Degradation Decolorization Affected factor Kinetic parameters
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