A novel procedure for acid-catalysed K2FeO4 oxidation of benzyl alcohol in organic phase |
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Authors: | Hua Song Zheng Guang Li Bao Hui Wang |
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Institution: | (1) Chemistry & Chemical Engineering College, Daqing Petroleum Institute, 199 Fazhan Rd., High-Tech Zone, 163318 Daqing, China |
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Abstract: | Recent investigations have shown that ferrate(VI) salts oxidize organic compounds in aqueous phases with fast reaction from
seconds to minutes and poor selectivity. Few studies have used ferrate(VI) in organic phases. The main issues are the poor
solubility of K2FeO4 in common organic solvents and the low reaction rate. Therefore the interests to date are focused on finding a more effective
catalyst in the organic oxidation. Up to now no work has been reported on acids as catalysis for the oxidative abilities of
K2FeO4 in organic phases. Here we present a novel procedure for oxidizing benzyl alcohol to benzaldehyde without an overoxidation
to benzoic acid by K2FeO4 in an organic phase. Using benzyl alcohol as a model, the catalytic activity of various acid solutions was measured. We found
that the reactivity of K2FeO4 to the oxidation of benzyl alcohol can be highly enhanced by addition of a small amount of acid solution at room temperature.
The catalytic ability of acid solutions follows the order acetic acid < oxalic acid < phosphomolybdic acid < phosphotungstic
acid. On the basis of a theoretical analysis, a reaction mechanism is proposed. This method provides a new green way for oxidizing
organic substances by K2FeO4 in nonaqueous media. |
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