| 大气中挥发性有机物(VOCs)对二次有机气溶胶(SOA)生成贡献的参数化估算 |
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| 引用本文： | 陈文泰,邵敏,袁斌,王鸣,陆思华.大气中挥发性有机物(VOCs)对二次有机气溶胶(SOA)生成贡献的参数化估算[J].环境科学学报,2013,33(1):163-172. |
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| 作者姓名： | 陈文泰 邵敏 袁斌 王鸣 陆思华 |
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| 作者单位： | 环境模拟与污染控制国家重点联合实验室,北京大学环境科学与工程学院,北京100871 |
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| 基金项目： | 国家杰出青年科学基金(No.41125018) |
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| 摘 要： | 大气中二次有机气溶胶(SOA)是PM25中的重要组成部分,挥发性有机物(VOCs)的光化学氧化是其主要来源之一.从VOCs转化生成SOA的过程非常复杂,参数化方法是一种相对简化的估算方式,可以用于区分不同VOCs物种对SOA生成的贡献.本文介绍了基于二产物和基于挥发性分级两种常用的参数化估算方法,并总结分析文献报道的SOA估算结果.文章中也指出现在的参数化估算还存在一些问题,如何准确量化VOCs向SOA的转化过程将是大气化学未来的重要研究工作.
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| 关 键 词： | 二次有机气溶胶 挥发性有机物 参数化 |
| 收稿时间： | 4/7/2012 12:00:00 AM |
| 修稿时间： | 2012/5/30 0:00:00 |
Parameterization of contribution to secondary organic aerosol (SOA) formation from ambient volatile organic compounds (VOCs) |
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| CHEN Wentai,SHAO Min,YUAN Bin,WANG Ming and LU Sihua.Parameterization of contribution to secondary organic aerosol (SOA) formation from ambient volatile organic compounds (VOCs)[J].Acta Scientiae Circumstantiae,2013,33(1):163-172. |
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| Authors: | CHEN Wentai SHAO Min YUAN Bin WANG Ming and LU Sihua |
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| Institution: | State Joint Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Science and Engineering, Peking University, Beijing 100871;State Joint Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Science and Engineering, Peking University, Beijing 100871;State Joint Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Science and Engineering, Peking University, Beijing 100871;State Joint Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Science and Engineering, Peking University, Beijing 100871;State Joint Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Science and Engineering, Peking University, Beijing 100871 |
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| Abstract: | Secondary organic aerosol (SOA) is a very important portion in mass concentration of ambient fine particles (PM2.5), and the volatile organic compounds (VOCs) are one of the most important precursors for SOA formation.Considering the complexity of the processes from the VOCs conversion to SOA production, the parameterization is a practical approach in estimating SOA formation potential, and hence in identifying the relative contributions of various VOC species to fine particles.Two estimation methods were introduced in this study, namely 2-products method and the volatility basis-set method, and the estimation results from recent literatures were compared.This work also discussed the existing problems in current parameterization methods.More attentions and detailed investigations should be paid in accurate quantification of VOC-to-SOA transformation in future atmospheric chemistry studies. |
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| Keywords: | secondary organic aerosol volatile organic compounds parameterization |
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