| Preparation of birnessite-supported Pt nanoparticles and their application in catalytic oxidation of formaldehyde |
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| 作者姓名： | Linlin Liu Hua Tian Junhui He Donghui Wang Qiaowen Yang |
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| 作者单位： | Functional Nanomaterials Laboratory and Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry (TIPC), Chinese Academy of Sciences, Beijing 100190, China;School of Chemical & Environmental Engineering, China University of Mining & Technology, Beijing 100083, China;Functional Nanomaterials Laboratory and Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry (TIPC), Chinese Academy of Sciences, Beijing 100190, China;Functional Nanomaterials Laboratory and Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry (TIPC), Chinese Academy of Sciences, Beijing 100190, China;Research Institute of Chemical Defense, Beijing 100083, China;School of Chemical & Environmental Engineering, China University of Mining & Technology, Beijing 100083, China |
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| 基金项目： | This work was supported by the National Natural Science Foundation of China (No. 20871118, 21007076), the Knowledge Innovation Program of the Chinese Academy of Sciences (CAS) (No. KSCX2-YW-G-059), the National Basic Research Program (973) of China (No. 2010CB934103), and the “Hundred Talents Program” of CAS. |
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| 摘 要： | Flaky and nanospherical birnessite and birnessite-supported Pt catalysts were successfully prepared and characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS) and N2 adsorption-desorption. Effects of the birnessite morphology and Pt reduction method on the catalytic activity for the complete oxidation of formaldehyde (HCHO) were investigated. It was found that flaky birnessite exhibited higher catalytic activity than nanospherical birnessite. The promoting effect of Pt on the birnessite catalyst indicated that the reduction method of the Pt precursor greatly influenced the catalytic performance. Flaky birnessite-supported Pt nanoparticles reduced by KBH4 showed the highest catalytic activity and could completely oxidize HCHO into CO2 and H2O at 50℃, whereas the sample reduced using H2-plasma showed lower activity for HCHO oxidation. The differences in catalytic activity of these materials were jointly attributed to the effects of pore structure, surface active sites exposed to HCHO and the dispersion of Pt nanoparticles.
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| 关 键 词： | birnessite manganese oxide noble metals formaldehyde oxidation |
| 收稿时间： | 15 July 2011 |
| 修稿时间： | 12 December 2011 |
Preparation of birnessite-supported Pt nanoparticles and their application in catalytic oxidation of formaldehyde |
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| Linlin Liu,Hua Tian,Junhui He,Donghui Wang,Qiaowen Yang.Preparation of birnessite-supported Pt nanoparticles and their application in catalytic oxidation of formaldehyde[J].Journal of Environmental Sciences,2012,24(6):1117-1124. |
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| Authors: | Linlin Liu Hua Tian Junhui He Donghui Wang and Qiaowen Yang |
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| Institution: | Functional Nanomaterials Laboratory and Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry (TIPC), Chinese Academy of Sciences, Beijing 100190, China;School of Chemical & Environmental Engineering, China University of Mining & Technology, Beijing 100083, China;Functional Nanomaterials Laboratory and Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry (TIPC), Chinese Academy of Sciences, Beijing 100190, China;Functional Nanomaterials Laboratory and Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry (TIPC), Chinese Academy of Sciences, Beijing 100190, China;Research Institute of Chemical Defense, Beijing 100083, China;School of Chemical & Environmental Engineering, China University of Mining & Technology, Beijing 100083, China |
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| Abstract: | Flaky and nanospherical birnessite and birnessite-supported Pt catalysts were successfully prepared and characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS) and N2 adsorption-desorption. Effects of the birnessite morphology and Pt reduction method on the catalytic activity for the complete oxidation of formaldehyde (HCHO) were investigated. It was found that flaky birnessite exhibited higher catalytic activity than nanospherical birnessite. The promoting effect of Pt on the birnessite catalyst indicated that the reduction method of the Pt precursor greatly influenced the catalytic performance. Flaky birnessite-supported Pt nanoparticles reduced by KBH4 showed the highest catalytic activity and could completely oxidize HCHO into CO2 and H2O at 50°C, whereas the sample reduced using H2-plasma showed lower activity for HCHO oxidation. The differences in catalytic activity of these materials were jointly attributed to the effects of pore structure, surface active sites exposed to HCHO and the dispersion of Pt nanoparticles. |
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| Keywords: | birnessite manganese oxide noble metals formaldehyde oxidation |
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