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Monitoring of heavy metal concentrations in home outdoor air using moss bags
Authors:Rivera Marcela  Zechmeister Harald  Medina-Ramón Mercedes  Basagaña Xavier  Foraster Maria  Bouso Laura  Moreno Teresa  Solanas Pascual  Ramos Rafael  Köllensperger Gunda  Deltell Alexandre  Vizcaya David  Künzli Nino
Institution:a Centre for Research in Environmental Epidemiology CREAL, Barcelona, Spain
b Municipal Institute of Medical Research (IMIM-Hospital del Mar), Barcelona, Spain
c Universitat Pompeu Fabra, Barcelona, Spain
d CIBER Epidemiología y Salud Pública (CIBERESP), Spain
e University of Vienna, Faculty of Life Sciences, Vienna, Austria
f Institute of Environmental Assessment and Water Research (IDÆA-CSIC), Barcelona, Spain
g Research Unit, Family Medicine, Girona, Jordi Gol Institute for Primary Care Research (IDIAP Jordi Gol), Catalan Institute of Health, Catalunya, Spain
h Department of Medical Sciences, School of Medicine, University of Girona, Spain
i University of Natural Resources and Applied Life Sciences, Vienna, Austria
j Polytechnic School, GREFEMA, University of Girona, Spain
k Swiss Tropical and Public Health Institute, Basel, Switzerland
l University of Basel, Basel, Switzerland
Abstract:One monitoring station is insufficient to characterize the high spatial variation of traffic-related heavy metals within cities. We tested moss bags (Hylocomium splendens), deployed in a dense network, for the monitoring of metals in outdoor air and characterized metals’ long-term spatial distribution and its determinants in Girona, Spain. Mosses were exposed outside 23 homes for two months; NO2 was monitored for comparison. Metals were not highly correlated with NO2 and showed higher spatial variation than NO2. Regression models explained 61-85% of Cu, Cr, Mo, Pb, Sb, Sn, and Zn and 72% of NO2 variability. Metals were strongly associated with the number of bus lines in the nearest street. Heavy metals are an alternative traffic-marker to NO2 given their toxicological relevance, stronger association with local traffic and higher spatial variability. Monitoring heavy metals with mosses is appealing, particularly for long-term exposure assessment, as mosses can remain on site many months without maintenance.
Keywords:Traffic-related air pollution  Outdoor exposure  Spatial distribution  Determinants  Buses  Particulate matter  Nitrogen dioxide
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