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聚丙烯中空纤维膜生物反应器净化复合芳香族VOCs
引用本文:王震文,修光利,詹天珍,徐方圆,吴来明,张萍,张大年.聚丙烯中空纤维膜生物反应器净化复合芳香族VOCs[J].环境工程学报,2013,7(6):2267-2272.
作者姓名:王震文  修光利  詹天珍  徐方圆  吴来明  张萍  张大年
作者单位:1. 华东理工大学,国家环境保护化工过程环境风险评价与控制重点实验室,上海 200237
2. 馆藏文物保护环境国家文物局重点科研基地(上海博物馆),上海,200050
基金项目:国家科技部"十一五"支撑计划资助(2010BAK67B15);中央高校基本科研业务费专项资金资助资助(WB1113005)
摘    要:采用中空纤维膜生物反应器(HFMBR)去除气态复合苯系物。挂膜后期,生物反应器的去除效率可以稳定达到80%左右(去除能力(EC)≥225 g/(m3.h))。研究了中空纤维膜生物反应器处理对于单一二甲苯以及混合二甲苯的性能,并且发现HFMBR对于去除单一二甲苯和混合二甲苯都有明显的效果,去除效率均达到90%以上;表明二甲苯之间竞争效应带来的相互抑制作用小。在低浓度的情况下,单一二甲苯和混合二甲苯的去除能力呈线性增加,在高浓度阶段,去除能力增加变缓。比较了混合二甲苯与甲苯联合降解,发现两者之间存在相互抑制作用,但相比传统生物反应器有明显的改善。与传统生物过滤系统比较而言,膜生物反应器有着很好的应用前景。

关 键 词:聚丙烯中空纤维膜  膜生物反应器  挥发性有机物(VOCs)  二甲苯
收稿时间:4/1/2012 12:00:00 AM
修稿时间:6/5/2012 12:00:00 AM

Treatment of mixtures of aromatic VOCs by a polypropylene hollow fiber menbrane bioreactor
Wang Zhenwen,Xiu Guangli,Zhan Tianzhen,Xu Fangyuan,Wu Laiming,Zhang Ping and Zhang Danian.Treatment of mixtures of aromatic VOCs by a polypropylene hollow fiber menbrane bioreactor[J].Techniques and Equipment for Environmental Pollution Control,2013,7(6):2267-2272.
Authors:Wang Zhenwen  Xiu Guangli  Zhan Tianzhen  Xu Fangyuan  Wu Laiming  Zhang Ping and Zhang Danian
Institution:State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science & Technology, Shanghai 200237, China;State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science & Technology, Shanghai 200237, China;State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science & Technology, Shanghai 200237, China;Key Scientific Research Base of Museum Environment, State Administration for Cultural Heritage, Shanghai Museum, Shanghai 200050, China;Key Scientific Research Base of Museum Environment, State Administration for Cultural Heritage, Shanghai Museum, Shanghai 200050, China;State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science & Technology, Shanghai 200237, China;State Environmental Protection Key Laboratory of Risk Assessment and Control on Chemical Processes, East China University of Science & Technology, Shanghai 200237, China
Abstract:The hollow fiber membrane bioreactor (HFMBR) was used to remove gaseous mixtures of benzene series. During biofilm colonization, the removal efficiency and elimination capacity (EC) of bioreactor reached around 80%, 225 g/(m3·h), respectively. The performance of the HFMBR for treating single and mixed xylene were investigated, and it was found that the HFMBR can effectively treat both single and mixed xylenes, and the removal efficiency was over 90%, which indicated that the inhibition effect between xylene species was weak. The removal capacity of single and mixed xylenes increased linearly when the inlet concentration was lower while the increase became slower at higher concentration. Through comparing degradation of mixed xylene with toluene, the inhibition effect between them was found. However, the inhabitation was still lower than the conventional bioreactor. The membrane bioreactor therefore has a promising prospect for application compared with conventional biofiltration process.
Keywords:polypropylene hollow fiber menbrane  menbrane bioreactor  volatile organic compounds(VOCs)  xylene
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