Chlorine speciation in seawater; a metastable equilibrium model for ClI and BrI species |
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| Authors: | Richard Sugam George R Helz |
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| Institution: | Public Service Electric and Gas Company 80 Park Plaza Newark, New Jersey 07101 USA;Department of Chemistry University of Maryland College Park, Maryland 20742 USA |
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| Abstract: | A thermodynamic model for the inorganic, fast-reacting fraction of the total residual oxidant produced by chlorination in marine waters reveals that BrI species are more stable than ClI species. At typical amino-N levels, HOBr, NBr3, and NHBr2 predominate. Data on organic byproducts of chlorination generally support the model calculations. |
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