Development of a High Purity Filter for High Temperature Particulate Sampling and Analysis

This paper is directed to those interested in measuring trace metals in high-temperature particulate emissions. Particulate handsheet filters with satisfactory purity, efficiency, thermal stability, cost, strength (about 1 lb/in.), and flexibility for analysis of particulates in gases up to 800°C have been made with 99.2% Si0₂ Microquartzfibers. Almost all purity requirements for optimum atomic absorption and flame emission spectrophotometric analysis for trace metals have been achieved. The filters appear highly promising for X-ray fluorescence analysis but should be further evaluated. Suitability of the filters for neutron activation analysis is uncertain and should also be further evaluated. Dioctyl phthal-ate (DOP) aerosol efficiencies of 99 to 99.99% have been achieved by using fibers of various diameters. The filters are insensitive to humidity, insoluble In most acids and organic solvents. The handsheet filters have a slightly alkaline pH, but similar filters have been made on a papermaking machine with a pH of 6.4. Cost is estimated to be about $2.00/ft².