Survey of Airborne 2,4-D in South-Central Washington

The extensive application of 2,4-D herbicides to wheat and other agricultural crops in the states of Washington and Oregon can produce "off-target" damage when the 2,4-D formulations are transported by the atmosphere to sensitive crops, such as grapes. During May-June of 1973 and April-June of 1974, a 2,4-D monitoring network in south-central Washington collected samples for subsequent herbicide analysis. The daily, 24 hr field samples were collected with differential Impactor-impinger air samplers and were routinely analyzed in the analytical laboratory by electron-capture gas chromatography. In addition, gas chromatography/mass spec-trometry was employed for positive identification of the 2,4-D esters and for comparative quantitative analysis. The complete sampling and analytical methodology, the 2,4-D concentration data for 1973 and 1974, the agricultural 2,4-D application records and crop Injury reports, and the concomitant meteorological data are described in this paper.