Relationship of Hydrocarbons to Oxidants in Ambient Atmospheres

The relation of ambient levels of hydrocarbons to the products of atmospheric photochemistry has proved to be an elusive problem. Models to account for the photochemical processes are available based on laboratory examination of simulated atmospheres. Likewise, dispersion models are available which, for nonreacting species, can predict air quality given knowledge of emission rates and meteorological variables. However, integration of the dispersion model with the photochemical model is as yet an unsolved problem. In this study an empirical approach was applied in which the only assumption made was that there exists a relationship between early morning average hydrocarbon concentrations and subsequent maximum hourly average oxidant concentrations. A direct examination of all available days in several cities shows that, at any given hydrocarbon level, there exists a limit on the amount of oxidant which can be generated. Specifically it shows that the average 6:00–9:00 A.M. concentration of 0.3 ppm C nonmethane hydrocarbon can be expected to produce a maximum hourly average oxidant concentration of up to 0.1 ppm.