| 二氧化硫与环己烷的光化学反应 |
| |
| 引用本文： | 杜尧国 郭海忱. 二氧化硫与环己烷的光化学反应[J]. 环境化学, 1994, 13(6): 530-535 |
| |
| 作者姓名： | 杜尧国 郭海忱 |
| |
| 作者单位： | 吉林大学环境科学系!长春130023 |
| |
| 摘 要： | 本文研究了ＳＯ２与环己烷在无氧及有氧体系中的光化学反应，观察到了白色烟雾有生成并凝聚，利用ＧＣ和ＧＣ／ＭＳ法确定了部分反应产物－环烯烃、醇、酮、二元酸酯、呋喃衍生物以及硫酸二甲酯等有机化合物，探讨了影响光化学反应的几种因素及反应机理。
|
| 关 键 词： | 二氧化硫 环己烷 光化学反应 |
THE PHOTOCHEMICAL REACTION OF SULFUR DIOXIDE AND CYCLOHEXANE |
| |
| Du Yaoguo Guo Haichen Zhang Lianshe Xu Zili. THE PHOTOCHEMICAL REACTION OF SULFUR DIOXIDE AND CYCLOHEXANE[J]. Environmental Chemistry, 1994, 13(6): 530-535 |
| |
| Authors: | Du Yaoguo Guo Haichen Zhang Lianshe Xu Zili |
| |
| Abstract: | In this paper , the photochemical reactions of sulfur dioxide and cyclohexane were studied in the presence and absence of oxygen , respectively. The formation of aersol and a series of products such as cyclenes, alcohol, ketones , esters, furan derivations and organic sulfur compounds were found by using GC and GC/MS. According to the characteres of such compounds and the theory of chemical kinetics , the mechanisms of these photochemical reactions were suggested. |
| |
| Keywords: | sulfur dioxide cyclohexane photochemical reaction. |
| 本文献已被 CNKI 维普 等数据库收录！ |
