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Zeolite (Na) modified by nano-Fe particles adsorbing phosphate in rainwater runoff
Authors:Lili Gan  Jiane Zuo  Bangmi Xie  Peng Li and Xia Huang
Institution:State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China;State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China;State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China;State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China;State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China
Abstract:Zeolite (Na) modified by self-synthesized nano-Fe particles was used as infiltration media to adsorb phosphate in rainwater runoff. The adsorption capacities increased up to 75 times that of natural zeolite at a saturated equilibrium phosphate concentration of 0.42 mg/L. The correlation of capacity and material-specific surface area indicated that specific surface area was not the key factor contributing to the capacity improvement. SEM and XRD analysis showed that chemical reaction between Fe and P to form new products like cacoxenite is the main reason for the increased capacity, and that the method of adding metal ions or particles to improve the adsorption capacity for phosphate is feasible.
Keywords:rainwater runoff  phosphate adsorption  nano-iron modification
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