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应用分光光度法监测大连湾海水COD
引用本文:徐学仁,张志忠,张国光,于涛,付云娜,蒋岳文.应用分光光度法监测大连湾海水COD[J].海洋环境科学,2004,23(3):58-60.
作者姓名:徐学仁  张志忠  张国光  于涛  付云娜  蒋岳文
作者单位:国家海洋监测中心,辽宁,大连,116023;国家海洋技术中心,天津,300111
基金项目:国家自然科学基金资助项目(2001AA635110)
摘    要:在大连湾采集了5个站位12个海水样品,应用分光光度法和规范法平行测定COD的含量。取1000mL现场海水用规范法平行测定5次,取平均值作为分光光度法的标准浓度值。用该海水的消光度计算未知样品的COD,计算公式:c2=c1E标/E测。测定结果表明两种方法基本相同,其相关系数r=0.9283。分光光度法可以代替规范法的硫代硫酸钠滴定法。

关 键 词:COD  分光光度法  大连湾
文章编号:1007-6336(2004)03-0058-03
修稿时间:2003年9月26日

Mornitoring of COD in seawater by the spectrometry in Dalian Bay
XU Xue-ren,ZHANG Zhi-zhong,ZHANG Guo-guang,YU Tao,FU Yun-na,JIANG Yue-wen.Mornitoring of COD in seawater by the spectrometry in Dalian Bay[J].Marine Environmental Science,2004,23(3):58-60.
Authors:XU Xue-ren  ZHANG Zhi-zhong  ZHANG Guo-guang  YU Tao  FU Yun-na  JIANG Yue-wen
Institution:XU Xue-ren~1,ZHANG Zhi-zhong~2,ZHANG Guo-guang~1,YU Tao~1,FU Yun-na~1,JIANG Yue-wen~1
Abstract:COD content of 12 seawater samples collected from 5 stations in Dalian Bay were measured by the spectrometry and titration separately. The sample of 1 000 mL seawater was analyzed 5 parallel times by the titration, and the average of the 5 analytical results was used as the standard concentration of COD. Based the absorbency and the concentration of this seawater sample, the COD content of other seawater samples were measured by the spectrometry and the analytical results was calculated by the formula c_2= c_1 E _s/ E _x. The analytical results indicate that the COD contents measured by the spectrometry and titration are very close, the correlation coefficient of which is 0.928 3. Through the experiment, the conclusion is that the spectrometry can substitute for the titration in measured COD content of seawater.
Keywords:COD  spectrometry  Dalian Bay
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