Cleaner tanning practices for tannery pollution abatement: Role of enzymes in eco-friendly vegetable tanning |
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| Authors: | Swarna V Kanth R Venba B Madhan NK Chandrababu S Sadulla |
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| Institution: | 1. College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi''an, 710021, China;2. National Demonstration Center for Experimental Light Chemistry Engineering Education (Shaanxi University of Science & Technology), Xi''an, 710021, China;1. College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an, 710021, China;2. National Demonstration Center for Experimental Light Chemistry Engineering Education (Shaanxi University of Science & Technology), Xi’an, 710021, Shaanxi, China;3. Department of Chemical and Environmental Engineering, Faculty of Engineering, University Putra Malaysia(UPM), 43400, Seri Kembangan, Selangor, Malaysia;4. Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an, 710072, China;1. College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi’an, 710021, China;2. National Demonstration Center for Experimental Light Chemistry Engineering Education (Shaanxi University of Science & Technology), Xi’an, 710021, Shaanxi, China;3. Laboratory of Plastics and Rubber Technology, Department of Physical Chemistry and Materials Science, Budapest University of Technology and Economics, H-1521 Budapest, P.O. Box 91, Hungary;4. Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Hungarian Academy of Sciences, H-1519 Budapest, P.O. Box 286, Hungary;1. National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, PR China;2. Key Lab. of Leather Chemistry and Engineering of Ministry of Education, Sichuan University, Chengdu, Sichuan 610065, PR China;1. Leather Processing Division, CSIR-CLRI, Adyar, Chennai 20, India;2. Chemical Engineering Division, CSIR-CLRI, Adyar, Chennai 20, India |
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| Abstract: | Concern about pollution related problems in the global scenario are persuading all the processing industries to adopt cleaner manufacturing practices. Thus, the leather industry is also under pressure to look for effective alternative tanning materials for chromium. Natural products like vegetable tannins are regaining importance. However, there are limitations in the use of vegetable tanning materials because of its high organic load in the effluent, which are difficult to degrade leading to high chemical oxygen demand (COD). Moreover, conventional vegetable tanning process requires partial pickling that involves the use of sodium chloride, to suppress osmotic swelling. This results in very high amount of total dissolved solid (TDS) content in wastewaters. In this investigation, an attempt has been made to design an eco-friendly vegetable tanning process combining pickle-free tanning and application of proteolytic enzymes to improve the exhaustion of vegetable tannins. Such an approach has resulted in more than 95% tannin exhaustion in the case of the experimental process, an increase of 10% compared with the conventional vegetable tanning process. The tanned leathers showed slight improvement in hydrothermal stability. Physical and tactile evaluation of experimental leathers has been better than conventionally tanned leathers. Surface colour values illustrated negligible variation in colour and shade between control and experimental leathers. The resultant leather showed opened up, split compact fibre structure that has been well coated, indicating that the enzyme assisted tanning process did not bring about any major change or destruction on the fibre structure of the leathers. The optimized system has been field tested in a commercial tannery. The results showed that the enzyme assisted tanning process is efficient in terms of improved quality of leather and also led to reduction in total solids (TS), chlorides and COD loads. The enzyme assisted tanning system presented appears to be a viable option for combating pollution arising from the conventional vegetable tanning system. |
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