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一种Cu-MOF缓蚀剂的复配研究
引用本文:张星,刘巍,李侠清,张全胜,冯雷雷,官庆卿,常峰.一种Cu-MOF缓蚀剂的复配研究[J].装备环境工程,2022,19(3):79-86.
作者姓名:张星  刘巍  李侠清  张全胜  冯雷雷  官庆卿  常峰
作者单位:中石化胜利油田石油工程技术研究院,山东 东营 257000,中石化胜利油田工程技术管理中心,山东 东营 257000
摘    要:目的 对Cu-MOF进行复配,探究其最佳复配比例,以增强Cu-MOF的缓蚀效果.方法 通过静态失重挂片、电化学测试和表面形貌分析等手段,探究Cu-MOF与硫脲、六亚甲基四胺复配前后对Q235碳钢在1 mol/L HCl介质中缓蚀行为的变化.结果 单独使用50 mg/L的Cu-MOF时,碳钢的腐蚀速率为2.83 g/(m...

关 键 词:Cu-MOF  复配  硫脲  六亚甲基四胺
收稿时间:2021/12/15 0:00:00
修稿时间:2022/1/7 0:00:00

Compounding of Cu-MOF Corrosion Inhibitor
ZHANG Xing,LIU Wei,LI Xia-qing,ZHANG Quan-sheng,FENG Lei-lei,GUAN Qing-qing,CHANG Feng.Compounding of Cu-MOF Corrosion Inhibitor[J].Equipment Environmental Engineering,2022,19(3):79-86.
Authors:ZHANG Xing  LIU Wei  LI Xia-qing  ZHANG Quan-sheng  FENG Lei-lei  GUAN Qing-qing  CHANG Feng
Institution:Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, 257000, China; Engineering Technology Management Center of Sinopec Shengli Oilfield, Dongying, 257000, China
Abstract:Thepurpose of this paper is to explored the optimal compounding ratio by compounding Cu-MOF,thereby obtain better corrosion inhibition effects of Cu-MOF. The corrosion inhibition behavior change of Cu-MOF before and after compounded with thiourea and hexamethylenetetramine on Q235 carbon steel in 1 mol/L HCl medium was investigated by the means of static weight-loss coupon test, electrochemical measurements and surface morphology analysis. When 50 mg/L Cu-MOF was used alone, the corrosion rate of carbon steel was 2.83 g/(m2.h). After using thiourea and hexamethylenetetramine with Cu-MOF for compounding, the weight-loss corrosion rate of carbon steel in hydrochloric acid solution has decreased with varying degrees, to 1.28 and 1.14 g/(m2.h) respectively. The compounding of thiourea and hexamethylenetetramine with Cu-MOF showed good synergistic effect. The protective film formed on the surface of carbon steel was denser and the corrosion inhibition efficiency was significantly improved.
Keywords:Cu-MOF  compound  thiourea  hexamethylenetetramine
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