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天然沸石负载La2O3-ZnO-TiO2光催化降解活性艳红K-2BP
引用本文:程刚, 周孝德, 李艳, 仝攀瑞, 王理明. 天然沸石负载La2O3-ZnO-TiO2光催化降解活性艳红K-2BP[J]. 环境工程学报, 2008, 2(12): 1626-1630.
作者姓名:程刚  周孝德  李艳  仝攀瑞  王理明
作者单位:1.西安理工大学水利水电学院,西安 710048;2.西安工程大学环境与化学工程学院,西安 710048; 2.西安工程大学环境与化学工程学院,西安 710048
基金项目:西安工程大学高级氧化功能实验室基金,陕西省教育厅专项科研计划
摘    要:利用80目天然斜发沸石作载体制备La2O3(0.5%)-ZnO(20%)-TiO2/沸石复合光催化剂,以20 W紫外灯为光源,在自制的光催化反应器中降解活性艳红K-2BP,考察了光照时间、空气通入量、催化剂用量、溶液初始浓度、H2O2与Fe3+投加量等对活性艳红K-2BP光催化降解率的影响。结果表明,当溶液初始浓度为60 mg/L,催化剂投加量为12 g/L,通气量为1 200 mL/min,光照2.5 h,活性艳红K-2BP的降解率可达99.2%;H2O2和Fe3+投加量为4 mL/L和3 g/L时,光照1 h活性艳红K-2BP降解率分别为100%和97.2%。紫外 可见吸收光谱显示,LZTZ光催化剂可有效降解印染废水。

关 键 词:La2O3-ZnO-TiO2   天然沸石   光催化   降解率   活性艳红
收稿时间:2008-06-13

Photocatalytic degradation of reactive brilliant red K-2BP by La2O3-ZnO-TiO2 loaded natural zeolite
Cheng Gang, Zhou Xiaode, Li Yan, Tong Panrui, Wang Liming. Photocatalytic degradation of reactive brilliant red K-2BP by La2O3-ZnO-TiO2 loaded natural zeolite[J]. Chinese Journal of Environmental Engineering, 2008, 2(12): 1626-1630.
Authors:Cheng Gang  Zhou Xiao-de  Li Yan  Tong Pan-rui  Wang Li-ming
Affiliation:2.School of Environment and Chemistry Engineering, Xi’an Polytechnic University, Xi’an 710048
Abstract:The composite photocatalytic materials La2O3(0.5%)-ZnO(20%)-TiO2/zeolite(LZTZ) were prepared when natural zeolite with 80 mesh was employed as the carriers. The effects of the photocatalytic degradation of reactive brilliant red K-2BP by using 20 W UV-lamp in self made photocatalytic reactor were researched through the illumination time, air flow rate, amount of LZTZ, initial concentration and the added quantity of H2O2 & Fe3+. The results show that when initial concentration was 60 mg/L, amount of LZTZ was 12 g/L, air flow rate was 1 200 mL/min and the illumination time was 2.5 hours, the decolorization rate of the reactive brilliant red K-2BP was 99.2%. When the added quantities of H2O2 and Fe3+ were 4 mL/L and 3 g/L, the decolorization rates of the reactive brilliant red K-2BP were 100% and 97.2% respectively under 1 hour of the illumination time. Besides, the UV-visible spectra revealed that the dye printing wastewater could be effectively degraded by LZTZ.
Keywords:La2O3-ZnO-TiO2
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