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分子印迹硅纳米改性氧化石墨烯复合材料的制备及其对双酚A的吸附研究
引用本文:夏秋鹏,王淳,王安.分子印迹硅纳米改性氧化石墨烯复合材料的制备及其对双酚A的吸附研究[J].四川环境,2021(1):28-35.
作者姓名:夏秋鹏  王淳  王安
作者单位:四川大学建筑与环境学院;中国科学院成都生物研究所
摘    要:制备了分子印迹硅纳米-氧化石墨烯复合吸附材料,并研究了复合材料对双酚A(Bisphenol A,BPA)的吸附性能.实验结果表明:复合吸附材料对BPA的吸附在35min内达到吸附平衡,Langmuir等温线模型得出最大吸附容量约为338.3mg/g;相对于BPA的结构类似物,对BPA具有良好的选择吸附性能;在溶液pH接...

关 键 词:分子印迹  硅纳米  氧化石墨烯  双酚A  吸附

Study on the Preparation of Molecularly Imprinted Silica-Graphene Oxide Composite Nanomaterial( MIP-GON) and its Adsorption for Bisphenol A
XIA Qiu-peng,WANG Chun,WANG An.Study on the Preparation of Molecularly Imprinted Silica-Graphene Oxide Composite Nanomaterial( MIP-GON) and its Adsorption for Bisphenol A[J].Sichuan Environment,2021(1):28-35.
Authors:XIA Qiu-peng  WANG Chun  WANG An
Institution:(College of Architecture&Environment,Sichuan University,Chengdu 610065,China;Chengdu Institute of Biology,Chinese Academy of Sciencei,Chengdu 610041,China)
Abstract:A composite nano-material(MIP-GON)was prepared by coupling multi-layer surface imprinted silica nano-particles(MIP)with graphene oxide(GO).The adsorption property of MIP-GON for Bisphenol A was investigated.The experimental results showed that the adsorption equilibrium of BPA by the composite adsorption material was reached within 35 mins.The adsorption isothermal was well fitted by the Langmuir model,with a maximum adsorption capacity of 338.3mg/g.The composite material has fairly good selectivity for Bisphenol A comparing with its structural analogs.The absorption efficiency of the material was pH dependent,with optimal absorption around pH of 6.In addition,low temperature was favorable for the adsorption process.The material has excellent cyclic adsorption properties.
Keywords:Molecular imprinting  silica nanoparticle  graphene oxide  Bisphenol A  selective adsorption
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