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热解温度对青霉素菌渣热解产物的影响
引用本文:司艳晓,胡长朝,党伟,徐孝轩. 热解温度对青霉素菌渣热解产物的影响[J]. 化工环保, 2021, 41(2): 190-195. DOI: 10.3969/j.issn.1006-1878.2021.02.011
作者姓名:司艳晓  胡长朝  党伟  徐孝轩
作者单位:中国石化石油勘探开发研究院,北京 100083
摘    要:将青霉素菌渣在400~700℃进行热解,研究了产物中热解炭、热解油及气体的产率,以及热解油的组成变化.实验结果表明:600℃时热解油产率最高,随着温度升高,热解炭的产率降低,气体的产率升高;热解油中含量最高的是含氧化合物,在400℃时质量分数达到最高值69.69%,含氧化合物的含量随着热解温度的升高而降低,酸和醇类是热...

关 键 词:青霉素菌渣  热解  含氧化合物  含氮有机化合物
收稿时间:2020-07-14

Effect of pyrolysis temperature on pyrolysis products of penicillin waste mycelium
SI Yanxiao,HU Changchao,DANG Wei,XU Xiaoxuan. Effect of pyrolysis temperature on pyrolysis products of penicillin waste mycelium[J]. Environmental Protection of Chemical Industry, 2021, 41(2): 190-195. DOI: 10.3969/j.issn.1006-1878.2021.02.011
Authors:SI Yanxiao  HU Changchao  DANG Wei  XU Xiaoxuan
Affiliation:Sinopec Petroleum Exploration and Development Research Institute,Beijing 100083,China
Abstract:The pyrolysis of penicillin waste mycelium was carried out at 400-700 ℃ to study the yields of pyrolysis carbon,pyrolysis oil and gas in the product,especially the composition change of pyrolysis oil. The experimental results show that:The pyrolysis oil yield reaches the highest at 600 ℃,while the pyrolysis carbon yield decreases and the gas production yield increased with the increase of temperature;The content of oxygenated compounds in pyrolysis oil is the highest with a maximum mass fraction of 69.69% at 400 ℃,and decreases with the increase of pyrolysis temperature;Acids and alcohols are the main oxygenated compounds in pyrolysis oil;The mass fraction of nitrogen-containing compounds increases with the increase of pyrolysis temperature with a maximum value of 30.64% at 700 ℃;Amides,pyridines,indoles,and nitrogen-containing heterocycles are the main nitrogen-containing compounds.
Keywords:penicillin waste mycelium  pyrolysis  oxygenated compound  nitrogenous compound  
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