Determination of PAN,PPN, PnBN and selected pentyl nitrates in Athens,Greece |
| |
| Institution: | 1. Huairou Eco-Environmental Observatory, College of Resources and Environment, University of Chinese Academy of Sciences, Beijing, 100049, China;2. State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China;3. Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China;4. State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, China;1. Eindhoven University of Technology, Department of Chemical Engineering and Chemistry, Separation Technology Group, Den Dolech 2, 5612 AZ Eindhoven, Netherlands;2. The Petroleum Institute, Chemical Engineering Department, P.O. Box 2533, Abu Dhabi, United Arab Emirates;1. Center of Excellence CETEMPS Universita'' degli studi di L''Aquila, Via Vetoio, 67010 Coppito, L''Aquila, Italy;2. Dipartimento di Scienze Fisiche e Chimiche, Universita'' degli studi di L''Aquila, Via Vetoio, 67010 Coppito, L''Aquila, Italy;3. Departement of Chemistry, University of York, UK;4. FAAM, Cranfileld University, UK;5. Observation Based Research (OBR), Met Office, FitzRoy Road, Exeter EX1 3PB, UK;6. School of Earth, Atmospheric and Environmental Science, The University of Manchester, UK;7. Department of Chemistry, University of Cambridge, UK;8. School of Environmental Sciences, University of East Anglia, UK;9. School of Chemistry, University of Leeds, UK;10. National Centre for Atmospheric Science, University of Leeds, UK;1. Programa de Pós-Graduação em Química, Instituto de Química, Universidade Federal Fluminense, Outeiro de São João Batista, s/n, 24020-141, Valonguinho, Centro, Niterói, RJ, Brazil;2. Laboratório de Química Analítica Fundamental e Aplicada, Departamento de Química Analítica, Instituto de Química, Universidade Federal Fluminense, Outeiro de São João Batista, s/n, 24020-141, Valonguinho, Centro, Niterói, RJ, Brazil |
| |
| Abstract: | Quasi-continuous measurements of PAN, PPN, PnBN and the alkyl nitrates—2-methyl-2-butyl nitrate, 3-pentyl nitrate and 2-pentyl nitrate were carried out in Athens using a simple cryoconcentration technique. The maximum mixing ratios measured were 6.6, 1.0 and 0.07 ppbv for PAN, PPN and PnBN, respectively, for the peroxyacyl nitrates, and 0.3, 0.09 and 0.03 ppb for 2-methyl-2-butyl nitrate, 2-pentyl nitrate and 3-pentyl nitrate, respectively. Mean ratios of PPN/PAN mixing ratios were 0.102 and of PnBN/PAN 0.012. 2PN/3PN mean ratios were 1.8 near the theoretical value of 1.6. All maximum values of measured nitrogenous compounds were associated with maximum mixing ratios of ozone and NOx and occurred when southwestern winds prevailed in association with a temperature inversion. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
