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西南某地粘土对U吸附的动态模拟实验研究
引用本文:李杰,施泽明,倪师军,张成江,张佩聪.西南某地粘土对U吸附的动态模拟实验研究[J].地球与环境,2012,40(4):618-622.
作者姓名:李杰  施泽明  倪师军  张成江  张佩聪
作者单位:1. 成都理工大学核技术与自动化工程学院,成都610059 山东省第六地质矿产勘查院,山东威海264209
2. 成都理工大学核技术与自动化工程学院,成都,610059
3. 成都理工大学地球科学学院,成都,610059
4. 成都理工大学材料与化学化工学院,成都,610059
基金项目:国防科工委核设施退役专项“非均匀介质中核素迁移与屏障研究”资助项目
摘    要:选择西南某地正电荷发育的弱酸性粘土TY4作为吸附介质,加5%Ca(OH)2作为添加剂制作模拟屏障,用模拟核废液对介质做动态淋滤实验,得出了铀浓度随流量、pH值的变化曲线。实验结果表明,随高度增加屏障的吸附性能增大,渗透系数减小。屏障在pH为11和9附近时吸附效果较强。

关 键 词:粘土  动态模拟实验  添加剂  U吸附  pH

Dynamic Simulation Experimental Research on Adsorption of Uranium on Clay Somewhere in Southwest China
LI Jie,SHI Ze-ming,NI Shi-jun,ZHANG Cheng-jiang,ZHANG Pei-cong.Dynamic Simulation Experimental Research on Adsorption of Uranium on Clay Somewhere in Southwest China[J].Earth and Environment,2012,40(4):618-622.
Authors:LI Jie  SHI Ze-ming  NI Shi-jun  ZHANG Cheng-jiang  ZHANG Pei-cong
Institution:1.College of Nuclear Technology and Automation Engineering,Chengdu University of Technology,Chengdu 610059,China;2.The 6th Geology and Mineral Resource Survey Institution in Shandong Province,Shandong, Weihai 264209,China;3.College of Geosciences,Chengdu University of Technology,Chengdu 610059,China; 4.College of Materials and Chemistry & Chemical Engineering,Chengdu University of Technology,Chengdu 610059,China)
Abstract:The TY4 clay which has a lot of positive charge with weak acidity somewhere in Southwest China was chosen.A dynamic experiment was deliberately designed to establish the curve of uranium's density related to flux and pH after appending 5% Ca(OH)2 as adsorption material to make simulating poles.The experimental results showed that the capability of adsorption was reinforced with increasing height and the average penetration coefficient was reduced.The pole's adsorption capability was reinforced when the pH was near 11 and 9.
Keywords:clay  dynamic simulation experiment  additive  U adsorption  pH
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