A model for the formation and degradation of bound residues of the herbicide 14C-isoproturon in soil. |
| |
Authors: | S Reuter M Ilim J C Munch F Andreux I Scheunert |
| |
Affiliation: | GSF-Institute of Soil Ecology, Neuherberg, Germany. |
| |
Abstract: | The humic monomer catechol was reacted with 14C-isoproturon and some of its metabolites, including 14C-4-isopropylaniline, in aqueous solution under a stream of oxygen. Only in the case of 14C-4-isopropylaniline, incorporation in oligomers, in fulvic acid-like polymers, and in humic acid-like polymers was observed. The main oligomer was identified by mass spectrometry as 4,5-bis-(4-isopropylphenylamino)-3,5-cyclohexadiene-1,2-dione. Oligomers and polymers containing bound 14C-4-isopropylaniline were subjected to biodegradation studies in a loamy agricultural soil during 55 days by quantifying 14CO2 evolved. In all cases, significant mineralization rates could be determined, which, however, were much smaller than those of free 14C-4-isoproturon and free 14C-4-isopropylaniline in the same soil. |
| |
Keywords: | |
|
|