Bioconcentration and uptake kinetics of chlorobenzenes in soy-bean roots |
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Authors: | H Kraaij DW Connell |
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Institution: | Griffith University, Faculty of Environmental Sciences, Nathan, Brisbane, QLD 4111, Australia |
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Abstract: | Excised soy-beanroots were exposed to an aqueous solution of five homologous chlorobenzenes in constant concentration. The results were in general agreement with water-lipid partitioning. The relationship between the bioconcentration factor and the octanol-water partition coëfficiënt (KOW) can be used to estimate bioconcentration. Effective equilibrium was reached within 2.5 hours for 1,2-di-, 1,3,5-tri- and 1,2,3,4-hexachlorobenzene and after a mean of 10.1 and 17.9 hours for penta- and hexachlorobenzene respectively. For 1,2-dichlorobenzene, 1,3,5-trichlorobenzene and 1,2,3,4-tetrachlorobenzene the elimination rate constant was > 4.1, and 0.46 and 0.30 hr−1 for penta- respectively hexachlorobenzene. In the range log Kow 4.56–5.77, k2 was negatively correlated with log KOW but k1 was not correlated with log KOW.. |
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