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臭氧液相氧化同时脱硫脱硝实验研究
引用本文:马双忱,苏敏,马京香,金鑫,孙云雪,赵毅.臭氧液相氧化同时脱硫脱硝实验研究[J].环境科学,2009,30(12):3461-3464.
作者姓名:马双忱  苏敏  马京香  金鑫  孙云雪  赵毅
作者单位:华北电力大学环境学院,保定,071003
基金项目:华北电力大学归国留学人员科研基金 
摘    要:在自制的鼓泡反应器上对臭氧(O_3)液相氧化分别脱硫脱硝技术进行了实验研究.结果表明,液相中O_3对NO能够有效氧化,SO_2的存在对NO的脱除具有一定的负面影响,而pH值对NO的脱除率影响较小.O_3]/NO]=1.1时,NO脱除率可达到89.6%.pH在3~11范围内,NO脱除率达80%以上.温度在20~65℃范围内,NO脱除率不发生明显变化.结合尾部洗涤装置后,可有效脱除SO_2和NOx,脱硫效率几乎达到100%,在O_3]/NO]=1.1时,可获得84.2%的脱硝效率.

关 键 词:脱硫脱硝  臭氧  液相氧化
收稿时间:2009/1/11 0:00:00
修稿时间:2009/3/10 0:00:00

Experimental Research for Simultaneous Removal of SO2 and NOx by Aqueous Oxidation of 3
MA Shuang-chen,SU Min,MA Jing-xiang,JIN Xin,SUN Yun-xue and ZHAO Yi.Experimental Research for Simultaneous Removal of SO2 and NOx by Aqueous Oxidation of 3[J].Chinese Journal of Environmental Science,2009,30(12):3461-3464.
Authors:MA Shuang-chen  SU Min  MA Jing-xiang  JIN Xin  SUN Yun-xue and ZHAO Yi
Institution:MA Shuang-chen,SU Min,MA Jing-xiang,JIN Xin,SUN Yun-xue,ZHAO Yi(School of Environment,North China Electric Power University,Baoding 071003,China)
Abstract:The removal of SO_2 and NO_x by aqueous oxidation of O_3 was studied by self-designed bubbling reactor.The results show that NO can be oxidized efficiently by O_3 in liquid phase,while the existence of SO_2 has a negative impact on the removal of NO and pH value has a little impact. The NO removal efficiency is 89.6% at O_3]/NO]=1.1.When the rang of pH value is in 3-11, NO removal efficiency can be achieved over 80%. At 20-65℃, NO removal efficiency has no change. Combining with wet scrubbing tower, SO_2 removal efficiency is nearly 100% and NOx removal efficiency is 84.2% at O_3]/NO]=1.1. SO_2 and NO_x can be removed effectively by aqueous oxidation of O_3 simultaneously.
Keywords:desulfurization and denitrification  ozone  aqueous oxidation
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