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Enhanced methane hydrate storage using sodium dodecyl sulfate and coal
Authors:Shu-Qing Hao  Sungho Kim  Yong Qin  Xue-Hai Fu
Institution:1. Key Laboratory of CBM Resources and Reservoir Formation Process Ministry of Education of China, School of Resource and Geosciences, China University of Mining and Technology, Xuzhou, 221116, China
2. State Key Laboratory for GeoMechanics and Deep Underground Engineering, University of Mining and Technology, Xuzhou, 221008, China
4. Department of Civil Engineering, Monash University, Victoria, 3840, Australia
3. Geotechnical and Hydrogeological Engineering Research Group, Monash University, Victoria, 3842, Australia
Abstract:A potential solution to reduce global warming is to store greenhouse gases. Greenhouse gas storage has been recently improved using several materials and techniques. However, the actual storage capacity is slow, limited, and costly. Here, we tested the use of an accelerating agent, sodium dodecyl sulfate, and coal to produce methane hydrate for methane storage. Experiments of storing methane gas in coal samples have been carried out under high pressures, 4 or 6 MPa, and low temperature of 273.15 K. Results reveal that sodium dodecyl sulfate improved the rate up to 58.26 cm3/min and the capacity up to 179.97 volume at standard temperature and pressure per unit volume of coal. This finding shows that sodium dodecyl sulfate is efficient to accelerate the formation of methane hydrate. We also found that storage capacity increased with pressure. We conclude that our method allows a gas storage capacity higher than any other medium materials reported previously.
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