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多孔矿物-聚磷酸铵对甲烷爆炸的协同抑制研究
引用本文:袁必和,陶红吉,孙亚如,王连聪,陈先锋,谭海. 多孔矿物-聚磷酸铵对甲烷爆炸的协同抑制研究[J]. 中国安全科学学报, 2021, 0(3): 41-46
作者姓名:袁必和  陶红吉  孙亚如  王连聪  陈先锋  谭海
作者单位:武汉理工大学安全科学与应急管理学院;煤科集团沈阳研究院有限公司煤矿安全技术国家重点实验室;武汉理工大学资源与环境工程学院
基金项目:国家重点研发计划项目(2017YFC0804705);国家自然科学基金资助(51703175);中央高校基本科研业务费资助项目(2020-zy-284);湖北省安全生产专项资金科技项目(KJZX202007004)。
摘    要:为探究新型多孔矿物(MTS)-聚磷酸铵(APP)复合粉体对甲烷-空气预混气爆炸的抑制效果,采用20 L球形爆炸装置开展多孔矿物、APP及其复合粉体在不同组成、不同添加浓度条件下的甲烷爆炸抑制试验,并使用热分析仪研究其热解行为.研究结果表明:当粉体添加量为0.100 g/L,多孔矿物与APP质量组成比为1∶3时,复合粉体...

关 键 词:多孔矿物(MTS)  聚磷酸铵(APP)  甲烷-空气预混气  抑爆  热稳定性

Study on synergistic suppression of methane explosion by porous mineral materials-ammonium polyphosphate composite powder
YUAN Bihe,TAO Hongji,SUN Yaru,WANG Liancong,CHEN Xianfeng,TAN Hai. Study on synergistic suppression of methane explosion by porous mineral materials-ammonium polyphosphate composite powder[J]. China Safety Science Journal, 2021, 0(3): 41-46
Authors:YUAN Bihe  TAO Hongji  SUN Yaru  WANG Liancong  CHEN Xianfeng  TAN Hai
Affiliation:(School of Safety Science and Emergency Management,Wuhan University of Technology,Wuhan Hubei 430070,China;State Key Laboratory of Coal Mine Safety Technology,CCTEG Shenyang Research Institute,Fushun Liaoning 113122,China;School of Resources and Environmental Engineering,Wuhan University of Technology,Wuhan Hubei 430070,China)
Abstract:In order to ascertain explosion suppression efficiency of a novel porous mineral material(Trade name: MTS)-APP powder inhibitor,a 20 L spherical explosion experimental apparatus was employed to study suppression effects of MTS,APP and their mixtures with different component proportions and added concentrations on methane-air explosion. Their pyrolysis behavior were evaluated by using a thermal analyzer. The results show that the synergistic inhibition effect of composite powder on methane explosion is most obvious when the addition of powder is 0. 100 g/L and the ratio of porous mineral to APP is 1 ∶ 3 with the weakening of each explosion parameter. Synergistic explosion suppression mechanism of MTS-APP powder consists of physical and chemical inhibition performances. The porous structure endows MTS with labyrinth effect,which enhances free radicals trapping ability. The successive endothermic decomposition reactions of MTS and APP can persistently absorb heat. Moreover,the decomposition products have the effects of dilution,cooling and isolation,and can consume the free radicals in the combustion reaction.
Keywords:porous mineral materials(MTS)  ammonium polyphosphate(APP)  premixed methane-air  explosion suppression  thermal stability
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