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V~(5+)/TiO_2-SiO_2-GF复合光催化剂制备及降解甲醛的研究
引用本文:李娟,檀科明,陈勇志,洪均.V~(5+)/TiO_2-SiO_2-GF复合光催化剂制备及降解甲醛的研究[J].环境科学与技术,2012(12):82-86.
作者姓名:李娟  檀科明  陈勇志  洪均
作者单位:重庆大学城市建设与环境工程学院
摘    要:采用溶胶-凝胶法制备了纯TiO2、TiO2-SiO2、V5+/TiO2-SiO2光催化剂,并分别负载于玻璃纤维布上,利用X射线衍射(XRD)和比表面及孔隙度(BET)分析技术对样品进行了表征。以甲醛的降解率来评价复合光催化剂的光催化活性。结果表明:玻璃纤维布预处理方式、TiO2与SiO2的复合配比、V的掺杂量、煅烧温度对纳米TiO2的光催化活性有影响。V5+/TiO2-SiO2复合光催化剂比表面积为143.74 m2/g,晶粒粒径为16.9 nm。

关 键 词:复合光催化剂  光催化活性  溶胶-凝胶法  甲醛

Preparation of V5+/TiO2-SiO2-GF Composite Photocatalyst and Degradation of Formaldehyde
LI Juan,TAN Ke-ming,CHEN Yong-zhi,HONG Jun.Preparation of V5+/TiO2-SiO2-GF Composite Photocatalyst and Degradation of Formaldehyde[J].Environmental Science and Technology,2012(12):82-86.
Authors:LI Juan  TAN Ke-ming  CHEN Yong-zhi  HONG Jun
Institution:(School of Urban Construction and Environmental Engineering,Chongqing University,Chongqing 400045,China)
Abstract:TiO2,TiO2-SiO2 and V5+/TiO2-SiO2 were prepared by sol-gel method,and then loaded on glass fibre.The samples were characterized by XRD and BET.Their photocatalytic properties were studied by photocatalytic degradation of formaldehyde.Results indicated that the photocatalytic activity of nano-TiO2 was mainly affected by factors such as pretreatment of glass fibre,composite ratio of TiO2 and SiO2,doping content of V5+,doping ratio and calcination temperature.Specific surface area of composite photocatalysts V5+/TiO2-SiO2 was 143.74 m2/g and grain particle size was 16.9 nm.
Keywords:composite photocatalyst  photocatalytic activity  sol-gel method  formaldehyde
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