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超声-微电解耦合处理难降解污染物研究进展
引用本文:王兵,高洁,任宏洋,莫正平,鲜波.超声-微电解耦合处理难降解污染物研究进展[J].环境科学与技术,2012(Z2):217-220.
作者姓名:王兵  高洁  任宏洋  莫正平  鲜波
作者单位:西南石油大学化学化工学院;中国石油天然气集团公司HSE重点实验室西南石油大学研究室;西南油气田分公司川中油气矿;塔里木油田勘探开发部
基金项目:油气藏地质及开发工程国家重点实验室开放基金(PLN1125)
摘    要:超声-微电解是近年来发展起来的一项水处理复合技术,此法借助超声波的空化效应、自由基作用和机械作用强化微电解反应。超声空化效应产生的空化泡在溃陷的瞬间形成高温高压,不仅有利于铁屑表面的传质作用,还引发了自由基反应,空化效应产生的微射流和冲击波促使电极表面不断更新,同时使反应液与铁屑、活性炭充分混合接触,有效的促进了原电池反应的快速进行,实现超声和微电解对工业废水中有机污染物的协同降解,提高对废水有机污染物的降解效率。

关 键 词:微电解  超声  难降解有机污染物  降解机理

Research Progress of Sono-Microelectrolysis Degradation of Non-degradable Organic Pollutants
WANG Bing,GAO Jie,REN Hong-yang,MO Zheng-ping,XIAN Bo.Research Progress of Sono-Microelectrolysis Degradation of Non-degradable Organic Pollutants[J].Environmental Science and Technology,2012(Z2):217-220.
Authors:WANG Bing  GAO Jie  REN Hong-yang  MO Zheng-ping  XIAN Bo
Institution:1.School of Chemistry and Chemical Engineering,Southwest Petroleum University,Chengdu 610500,China;2.CNPC Key Laboratory of HSE,Research Laboratory of Southwest Petroleum University,Chengdu 610500,China;3.Central Sichuan Oil and Gas District,PetroChina Southwest Oil and Gasfield Company,Suining 629000,China;4.Institute of Petroleum Exploration and Development,PetroChina Tarim Oilfield Company,Kuerle 841000,China)
Abstract:Sono-Microelectrolysis degradation of non-degradable organic pollutants in wastewater is a newly developed composit technology of wastewater treatment.In this process,the efficiency of micro-electrolysis is promoted by ultrasonic cavitation,free radical and mechanical effect.High pressure and temperature will be formed when the cavitation bubbles collapse in the moments,it is not only conducive to the mass transfer of the iron surface,but also lead to free radical reaction.Mechanical effect promotes the electrode surface continuously updated,at the same time,the reaction system is fully mixed by the effect.Thus synergetic degradation of non-degradable organic pollutants is achieved and the efficiency is increased.
Keywords:micro-electrolysis  ultrasound  non-degradable organic pollutants  degradation mechanism
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