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A new photon kinetic-measure based on the kinetics of electron-hole pairs in photodegradation of textile wastewater using the UV-H2O2FS-TiO2 process
Authors:SHIGWEDHA Nditange  HUA Zhao-zhe and CHEN Jian
Institution:1. Laboratory of Environmental Biotechnology,School of Biotechnology,Southern Yangtze University,Wuxi 214036,China
2. Laboratory of Environmental Biotechnology,School of Biotechnology,Southern Yangtze University,Wuxi 214036,China;KeyLaboratory of Industrial Biotechnology,Ministry of Education,Southern YangtzeUniversity,Wuxi 214036,China
Abstract:Actual textile wastewater and synthesized wastewater containing various textile dyes were photocatalytic degraded by the UVH2O2Fs-TiO2 process in an annular-flow photocatalytic reactor.In this process,a photon kinetic-measure was adopted to obtain constant rates of dyes decomposition.It was theorized that,by illumination at difierent UV frequencies.the electrons within the semiconductor were excited from the valence band to the conduction band,yielding the formation of electron-hole palrs which are the pre-requisites for photocatalysis.CPT(critical photonic time)exposure required to cause 90%of vibrations between the double and single bonds along the molecular chain of the dyes to be oxidized.was taken to measure the photocatalytic activities.The CPTs varied with the frequencies of the UV spectral areas.The derivatization of CPT from the first-order kinetic law was presented.
Keywords:critical photonic time(CPT)  photon efficiency  UV frequencies  regression line  textile wastewater  process  textile wastewater  photodegradation  kinetics  based  derivatization  CPTs  taken  measure  photocatalytic activities  exposure  cause  double  single  molecular  chain  critical  time  yielding  formation
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