Structure elucidation of the three most important toxaphene congeners by X-ray analysis |
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Authors: | Gerlinde Frenzen Dominik Hainzl Jürgen Burhenne Harun Parlar |
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Institution: | Department of Chemistry, University of Kassel, Heinrich-Plett-Str. 40, D-34109, Kassel, Germany |
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Abstract: | Three of the most frequently detected toxaphene components in environmental samples are the chlorobornanes 2-exo,3-endo,5-exo,6-endo,8b,8c,10a,10b-octachlorobornane (Parlar No. 26); 2-exo,3-endo,5-exo,6-endo,8b,8c,9c,10a,10b-nonachlorobornane (Parlar No. 50), and 2,2,5,5,8b,8c,9c,10a,10b-nonachlorobornane (Parlar No. 62), whose structures could not be completely elucidated by spectroscopical methods. This paper now describes the X-ray structure analysis of the three compounds and presents their exact crystal structure. |
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