Concentrations,properties, and health risk of PM2.5 in the Tianjin City subway system

A campaign was conducted to assess and compare the personal exposure in L3 of Tianjin subway, focusing on PM_2.5 levels, chemical compositions, morphology analysis, as well as the health risk of heavy metal in PM_2.5. The results indicated that the average concentration of the PM_2.5 was 151.43 μg/m³ inside the train of the subway during rush hours. PM_2.5 concentrations inside car under the ground are higher than those on the ground, and PM_2.5 concentrations on the platform are higher than those inside car. Regarding metal concentrations, the highest element in PM_2.5 samples was Fe; the level of which is 17.55 μg/m³. OC is a major component of PM_2.5 in Tianjin subway. Secondary organic carbon is the formation of gaseous organic pollutants in subway. SEM–EDX and TEM–EDX exhibit the presence of individual particle with a large metal content in the subway samples. For small Fe metal particles, iron oxide can be formed easily. With regard to their sources, Fe-containing particles are generated mainly from mechanical wear and friction processes at the rail–wheel–brake interfaces. The non-carcinogenic risk to metals Cr, Ni, Cu, Zn and Pb, and carcinogenic hazard of Cr and Ni were all below the acceptable level in L3 of Tianjin subway.