Photocatalytic degradation of dichlorvos in aqueous TiO2 suspensions |
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Authors: | Tatiana Oncescu Mihaela I. Stefan Petruta Oancea |
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Affiliation: | (1) Department of Physical Chemistry, University of Bucharest, Bd. Regina Elisabeta, no. 4-12, 030018 Bucharest, Romania;(2) Trojan Technologies, 3020 Gore Road, London, ON, Canada, N5V4T7 |
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Abstract: | Introduction In the present work, we explored the kinetics of dichlorvos (2,2-dichlorvinyl dimethyl phosphate, DDVP) decay through UV-A light-induced TiO2 photocatalysis at pH 4 and 9, and the formation of degradation intermediates and final products under specific experimental conditions. Experimental observations and theoretical considerations allowed us to suggest the degradation mechanism of DDVP by the UV/TiO2 process in aqueous solution. |
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