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低温等离子体处理恶臭废气研究
引用本文:马竞涛,周则飞,吴祖成,吕功煊,俞仁明.低温等离子体处理恶臭废气研究[J].环境工程,2007,25(6):46-49.
作者姓名:马竞涛  周则飞  吴祖成  吕功煊  俞仁明
作者单位:1. 中国科学院兰州化学物理研究所,甘肃,兰州,730000;中国石化镇海炼化公司技术中心,浙江,宁波,315207
2. 中国石化镇海炼化公司技术中心,浙江,宁波,315207
3. 浙江大学环境科学研究所,浙江,杭州,310027
4. 中国科学院兰州化学物理研究所,甘肃,兰州,730000
5. 中国石化镇海炼化公司,浙江,宁波,315207
摘    要:用低温等离子处理恶臭气是一门新兴的技术。通过对典型的恶臭物质硫化氢、乙硫醇、苯、甲苯等恶臭物质的低温等离子脱除试验,结果表明:采用电晕放电形式的低温等离子体处理恶臭废气是可行的,停留时间越长、电压越高脱除效果越好,当停留时间>9s,电压>20kV时恶臭物质的去除率基本>90%,进一步延长停留时间和升高电压,去除效率并不会大幅度提高。低浓度的烷烃背景气体对恶臭的脱除效率基本无影响,高浓度的烷烃背景气体使恶臭物的脱除效率下降,较高浓度氢气的存在也会降低恶臭物的脱除效率,而氧气浓度的提高可以显著提高硫化氢脱除率。

关 键 词:等离子  废气处理  恶臭  硫化氢  硫醇    甲苯
收稿时间:2007-02-15
修稿时间:2007年2月15日

RESEARCH ON THE REMOVAL OF ODOR SUBSTANCES BY LOW TEMPERATURE PLASM
Abstract:Using low temperature plasma to treat odor gas is a newly emerging technology.It was studied the removal of some typical odor substances(i.e.hydrogen sulfide,ethyl mercaptan, benzene,and toluene) by low temperature plasma treatment.The results show:using corona discharge plasma to treat odor gas is practicable; the longer the residence time and the higher the voltage,the better the removal effect;when the residence time is longer than 9 s and the voltage is higher than 20 kV ,the odor removal efficiency is basically above 90%; further increasing the residence time and the voltage won't dramatically increase the removal efficiency; basically,the alkane background gas with a low concentration has no effect on the odor removal efficiency,while the alkane background gas with a high concentration will decrease the odor removal efficiency; besides, the presence of hydrogen with a higher concentration will also decrease the odor removal efficiency,while increasing the concentration of oxygen will remarkably increase the removal efficiency of hydrogen sulfide.
Keywords:plasma  waste gas treatment  odor  hydrogen sulfide  mercaptan  benzene and toluene
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