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活性炭-Fenton组合法去除水中PAEs的研究
引用本文:孙大贵,陶长元,刘作华,杜军,刘仁龙.活性炭-Fenton组合法去除水中PAEs的研究[J].环境科学,2007,28(12):2734-2739.
作者姓名:孙大贵  陶长元  刘作华  杜军  刘仁龙
作者单位:重庆大学化学化工学院,重庆,400030;重庆大学化学化工学院,重庆,400030;重庆大学化学化工学院,重庆,400030;重庆大学化学化工学院,重庆,400030;重庆大学化学化工学院,重庆,400030
基金项目:国家创新研究群体科学基金项目(50621403);重庆市自然科学基金项目(CSCT2005BB7261)
摘    要:采用活性炭-Fenton组合方法催化氧化去除水中的邻苯二甲酸酯(PAEs),研究了H2O2、Fe2+-、H2O2/Fe2+-及活性炭的用量、pH值、反应时间以及PAEs的初始浓度等对水中PAEs去除率的影响.结果表明,在Fenton试剂与活性炭的协同作用下,对PAEs具有较好的去除效果.PAEs水溶液(DMP、DEP、DBP、DOP各为12 mg·L-1),经活性炭-Fenton法处理15 h后,PAEs的平均去除率可达到99.1%.

关 键 词:活性炭  Fenton试剂  邻苯二甲酸酯
文章编号:0250-3301(2007)12-2734-06
收稿时间:2007-01-21
修稿时间:2007-03-27

Removal of PAEs by Combined Activated Carbon-Fenton Process
SUN Da-gui,TAO Chang-yuan,LIU Zuo-hu,DU Jun and LIU Ren-long.Removal of PAEs by Combined Activated Carbon-Fenton Process[J].Chinese Journal of Environmental Science,2007,28(12):2734-2739.
Authors:SUN Da-gui  TAO Chang-yuan  LIU Zuo-hu  DU Jun and LIU Ren-long
Institution:College of Chemistry & Chemical Engineering, Chongqing University, Chongqing 400030, China. daguisun@126.com
Abstract:Removal of PAEs by combined process of activated carbon-Fenton was investigated. Factors associated with PAEs removal ratio following amount of activated carbon, dosages of oxidant, catalyst, initial concentration of PAEs, pH value and reaction time were studied. Results showed that high purification performance could be obtained by the synergetic effect of Fenton reagent and activated carbon. Average removal ratio of PAEs was 99.1% for the solution containing 12 mg x L(-1) DMP, DEP, DBP, DOP respectively by the activated carbon-Fenton process for 15 h.
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