Abstract: | The use of lignin degrading fungi for decomposition of a wide variety of xenobiotics has become an area of intensive research. One distinct advantage of lignin degrading fungi over bacteria is that they do not require preconditioning to a particular pollutant prior to transformation. This degradative ability has been attributed to a nonspecific and nonstereoselective extracellular lignin-degrading enzymatic system (ligninase) which is induced by the fungi under nitrogen or carbon-limiting conditions (Reid, 1979). Ligninases (lignin-peroxidases) are responsible for the initial oxidative attack on lignin and other complex molecules via formation of a free radical thereby leading to depolymerization of complex molecular structures. Potential degradative ability of peroxidases may extend to include (1) sorbed contaminants, (2) high molecular-weight, hydrophobic contaminants, and (3) complex mixtures of chemicals typical of a contaminated site. |