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次氯酸钠处理水煤气废水中的氧化还原电位变化研究
引用本文:张庆芳,朱永斌,李金平,贾小宁,赵祥. 次氯酸钠处理水煤气废水中的氧化还原电位变化研究[J]. 四川环境, 2009, 28(4): 13-15,19
作者姓名:张庆芳  朱永斌  李金平  贾小宁  赵祥
作者单位:兰州理工大学石油化工学院,兰州,730050
基金项目:国家高技术研究发展计划(863计划)项目 
摘    要:介绍了利用次氯酸钠的强氧化作用来处理含硫水煤气废水。NaClO与水中S^2-等还原性物质的反应为典型的氧化还原反应,随着S^2-的被氧化,其氧化还原电位是变化的。针对这点,本文主要研究NaClO的投加量对S^2-氧化还原电位的影响,并以此来控制实际工程中NaClO的投加量,防止NaClO的过量投加带来对设备的腐蚀和对水煤气质量的影响。

关 键 词:水煤气生产废水  次氯酸钠氧化  氧化还原电位

Variations of Oxidation-Reduction Potential during Treatment of Wastewater from Water Gas Using Sodium Hypochlorite
ZHANG Qing-fang,ZHU Yong-bin,LI Jin-ping,JIA Xiao-ning,ZHAO Xiang. Variations of Oxidation-Reduction Potential during Treatment of Wastewater from Water Gas Using Sodium Hypochlorite[J]. Sichuan Environment, 2009, 28(4): 13-15,19
Authors:ZHANG Qing-fang  ZHU Yong-bin  LI Jin-ping  JIA Xiao-ning  ZHAO Xiang
Affiliation:( School of Petrochemical Engineering of Lanzhou University of Technology, Lanzhou 730050, China)
Abstract:The method of treatment of water-gas wastewater containing S2- using strong oxidation of sodium hypochlorite is introduced. The reaction of NaCIO and reducing substances like S2- is a typical oxidation-reduction reaction. The reduction-oxidation potential keeps changing during the oxidation of S2-. In this regard, this paper mainly focuses on the effect of NaClO dosage on reduction-oxidation potential of S2- , based on which the dosage of NaClO can be controlled in practical projects to avoid equipment erosion and bad influence on water gas quality due to excessive dosage.
Keywords:Water gas wastewater  sodium hypochlorlte  oxidation-reduction potential
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