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Interaction of higher marine fungi with the herbicide atrazine. III. Adsorption of atrazine to the marine fungus Dendryphiellasalina
Authors:Mark J Schocken  Marilyn K Speedie
Institution:Department of Medicinal Chemistry/Pharmacognosy University of Maryland at Baltimore 636 West Lombard Street Baltimore, Maryland 21201, USA
Abstract:The adsorption of the herbicide 14C-atrazine to the marine fungus Dendryphiellasalina was studied using sodium azide as an inhibitor of active uptake. Adsorption of atrazine (94 ppb) was found to reach equilibrium within six hours. Adsorption as a function of concentration (9.4 to 468 ppb) conformed to the empirically derived Freundlich equation giving a K value of 6.2. Atrazine on the fungal cell surface was easily desorbed by successive artificial seawater washes indicating a relatively loose binding. The ability of the marine fungus D.salina to remove 14C-atrazine from an artificial seawater medium suggests an environmental role in the transport and redistribution of atrazine in estuaries.
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