Optimization of sampling for the determination of mean radium-226 concentration in surface soil

There are thousands of properties in the United States on which the soil has been contaminated to some degree with uranium mill tailings. An effort is now underway by the United States Department of Energy to identify sites contaminated with tailings and to perform remedial action when ²²⁶Ra levels exceed current guidelines. Because of the large number of sites involved, it is imperative that sample collection be performed in a cost-effective manner. In this paper we describe the results of a study in which we compared the efficiencies of different methods of sample collection in order to determine an optimal method for estimating the mean ²²⁶Ra concentration in soil. The study involved a field experiment in which extensive sampling was performed on sites known to be contaminated with uranium tailings. The experiment was designed to identify the advantages and limitations of composite sampling, the relative merits of random and uniformly spaced sample collection, the use of field gamma measurements for supplementing and reducing soil sample collection, and practical levels of accuracy and precision that can be obtained. Conclusions regarding gamma measurements are unique to ²²⁶Ra contamination. On the other hand, conclusions concerning composite sampling and random versus uniformly spaced sampling may depend primarily on the way the contamination was spread by man and hence may not be unique to ²²⁶Ra.Research sponsored by the Department of Remedial Action Projects, Office of Terminal Waste Disposal, U. S. Department of Energy under contract DE-AC05-84OR21400 with the Martin Marietta Energy Systems, Inc.ORNL—Grand Junction Office, Grand Junction, Colorado.