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基于入口NOx质量浓度修正的脱硝系统多模型预测控制策略及其应用案例
引用本文:尹贵豪, 赵中阳, 李钦武, 邵宇浩, 谭畅, 陈竹, 翁卫国, 郑成航. 基于入口NOx质量浓度修正的脱硝系统多模型预测控制策略及其应用案例[J]. 环境工程学报, 2022, 16(6): 1879-1891. doi: 10.12030/j.cjee.202105036
作者姓名:尹贵豪  赵中阳  李钦武  邵宇浩  谭畅  陈竹  翁卫国  郑成航
作者单位:1.浙江大学能源清洁利用国家重点实验室,国家环境保护燃煤大气污染控制工程技术中心,杭州 310027; 2.浙江浩普环保工程有限公司,杭州 310013
基金项目:国家重点研发计划项目(2020YFB0606203-4);山东省重大科技创新工程项目(2019JZZY010403);浙江省重点研发计划(2021C03165)
摘    要:建立不同锅炉工况下基于欧式距离聚类的总给煤量长短期记忆神经网络预测模型,对入口处的NOx质量浓度数据进行修正,其验证集上的均方根误差为3.53 mg·m-3。该结果优于常见的回归方法深度神经网络与随机森林回归的预测结果。以此为基础,研究了基于入口NOx质量浓度修正的多模型预测控制(MMPC),设计并进行了脱硝系统仿真。仿真结果表明,与原有控制条件相比,基于入口NOx质量浓度修正的MMPC策略使脱硝系统出口NOx质量浓度波动幅度减小了63.7%,并能满足出口质量浓度指标为40 mg·m-3时的控制要求,实现卡边控制。现场工程应用结果表明:在高、中、低负荷正常运行的工况条件下,入口修正-MMPC策略可将出口NOx质量浓度波动分别控制在±10.6 mg·m−3、±5.5 mg·m−3、±4.9 mg·m−3,以标准差来衡量波动幅度即分别减小了53.4%、74.7%、64.6%,此控制水平优于原有控制效果;在出口NOx质量浓度易超标并出现高浓度氨逃逸的快速变负荷工况下,升、降负荷出口NOx质量浓度波动分别控制在±6 mg·m−3、±5 mg·m−3,此控制水平仍优于原有控制效果。本研究的入口修正-MMPC控制策略可实现不同负荷、工况下的喷氨控制,减小出口NOx波动幅度,降低后续设备低温腐蚀的风险,从而提高SNCR/SCR联合脱硝系统运行的经济性和安全性。

关 键 词:选择性非催化还原和选择性催化还原联合脱硝   循环流化床   NOx质量浓度测量修正   多模型预测控制   超低排放
收稿时间:2021-05-08

Multi-model predictive control of denitrification system based on modification of inlet NOx mass concentration and its application case
YIN Guihao, ZHAO Zhongyang, LI Qinwu, SHAO Yuhao, TAN Chang, CHEN Zhu, WENG Weiguo, ZHENG Chenghang. Multi-model predictive control of denitrification system based on modification of inlet NOx mass concentration and its application case[J]. Chinese Journal of Environmental Engineering, 2022, 16(6): 1879-1891. doi: 10.12030/j.cjee.202105036
Authors:YIN Guihao  ZHAO Zhongyang  LI Qinwu  SHAO Yuhao  TAN Chang  CHEN Zhu  WENG Weiguo  ZHENG Chenghang
Affiliation:1.State Key Laboratory of Clean Energy Utilization, State Environmental Protection Center for Coal-Fired Air Pollution Control, Zhejiang University, Hangzhou 310027, China; 2.Zhejiang Hope Environmental Protection Engineering Co. Ltd., Hangzhou 310013, China
Abstract:A composite long short-term memory neural network was trained to correct the lag of inlet NOx mass concentration, on dataset divided by the Euclidean distance of the total coal supply of the boiler under typical working conditions. The root mean squared error on the verification dataset was 3.53 mg·m−3, which was better than the prediction results of common regression methods, such as deep neural network and random forest regression. On this basis, the Multi-model Predict Control (MMPC) strategy based on the correction of the inlet NOx mass concentration was studied, and the denitration system simulation was designed and carried out. The simulation result shows that compared with previous control, the MMPC with inlet NOx mass concentration correction makes the fluctuation range of outlet NOx mass concentration reduced by 63.7%, and it can also meet the control requirements when setting outlet mass concentration at 40 mg·m−3. The results of field application indicated that under operation conditions of high, medium and low load, the MMPC with inlet NOx mass concentration correction can control the outlet NOx mass concentration fluctuation between ±10.6, ±5.5 and ±9 mg·m-3, and the fluctuation range was reduced by 53.4%, 74.7% and 64.6% respectively by standard deviation. Then, under the condition of fast variable load, it is easy to happen that emission of NOx mass concentration at the outlet exceeds the standard and ammonia escapes at high concentration. However, the fluctuation of NOx mass concentration at the outlet of load up and load down coditionis controlled respectively within ± 6 and ±5 mg·m−3 by MMPC with inlet NOx mass concentration correction. It proves that the control performance is better than the original control effect. Above all, under different loads and operation conditions, the MMPC with inlet NOx mass concentration correction strategy studied in this paper can well control the amount of ammonia injection, reduce the fluctuation of NOx mass concentration at the outlet, minimize the risk of low temperature corrosion of subsequent equipment, and consequently improve the economy and safety of SNCR/SCR coupling denitration system.
Keywords:SNCR and SCR combined denitrification system  circulating fluidized bed  NOx<  sub> mass concentration measurementcorrection  multi-model predict control  ultra-low emission
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