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光催化氧化与生物氧化组合技术对染料化合物降解研究
引用本文:王怡中,陈梅雪,胡春,王菊思.光催化氧化与生物氧化组合技术对染料化合物降解研究[J].环境科学学报,2000,20(6):772-775.
作者姓名:王怡中  陈梅雪  胡春  王菊思
作者单位:中国科学院生态环境研究中心,环境水化学国家重点实验室,北京,100085
基金项目:中国科学院资助项目,中国科学院知识创新工程项目,国家科技攻关项目,29637010;59878051,RCEES99005,96-909-05-03-02,,,
摘    要:将多相光催化氧化法与生物氧化法相结合,探讨两种组合技术对染料化合物的降解。实验选用100ppm的甲基橙和典型实验溶液,适当配以一定浓度范围的生活污水,以保证生物菌种的生存条件。实验结果证明先生物氧化、后光催化氧化是一种比较好的组合方式,24h生物氧化,溶液COD去除达69.68%,色度去除达22.39%,随后光催化氧化1h,COD去除达84.65%,色度去除达91.31%。由此说明,这种组合方式可以体现出两种反应的互补性,尤其对生化处理后的残留色度有明显的改善。

关 键 词:染料化合物  光催化氧化  生物氧化  废水处理  降解
收稿时间:9/4/1999 12:00:00 AM
修稿时间:1999-09-04

A study of dye degradation in the combination process of photocatalytic oxidation with biochemical oxidation
WANG Yizhong,CHEN Meixue,HU Chun and WANG Jusi.A study of dye degradation in the combination process of photocatalytic oxidation with biochemical oxidation[J].Acta Scientiae Circumstantiae,2000,20(6):772-775.
Authors:WANG Yizhong  CHEN Meixue  HU Chun and WANG Jusi
Institution:State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Science, Chinese Academy of Science, Beijing 100085,State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Science, Chinese Academy of Science, Beijing 100085,State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Science, Chinese Academy of Science, Beijing 100085 and State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Science, Chinese Academy of Science, Beijing 100085
Abstract:It is difficuit to degrade the dyeing effluent by traditional biological process due to the nonbiodegradable nature.A combination technique of photocatalytic oxidation with biochemical oxidation for dye degradation was studies.The result showed that the combination technique of biochemical and photocatalytic oxidation worked very well.For example,a 100?ppm Methyl Organge solution,the COD (chemical oxidation demand) removal and color removal were 69.67% and 22.39% respectively after the 24?h biological treatment;Consequently,after 1?h photocatalytic oxidation,the COD removal and color removal of this solution were further increased to 84.65% and 91.31% respectively.It might be developed as an effective method to remove the remained color of dyeing effluent after traditional biological treatment.
Keywords:dye compound  photocatalytic oxidation  biochemical oxidation  combination technigue
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