用加速溶剂提取仪提取污染土壤中的有机氯农药

研究加速溶剂萃取对土壤中有机氯农药的提取效果,并与索氏提取法进行比较。结果表明,加速溶剂萃取对土壤中滴滴涕的回收率明显高于索氏提取,对土壤中BHC的提取能力与索氏提取相当。用该方法测定了天津污灌区和非污灌区土壤样品中的有机氯农药残留量。结果表明,α-BHC、β-BHC、δ-BHC、γ-BHC、p,p’-DDE、p,p’-DDD、p,p’-DDT、o,p’-DDT的检出率为100％,这些有机氯农药在污灌旱地和稻田地的残留量分别为7．5－71．1ng/g和3．0－16．5ng/g。非污灌的旱地中有机氯农药的残留量为3．1－17．6ng/g。

Extraction of organochlorine pesticides using ASE from wastewater irrigated agricultural soil

The extraction efficiency of accelerated solvent extraction (ASE) was studied for organochlorine pesticide residuals in soil and compared with that of Soxhlet. The results showed that the efficiency of ASE was generally better than Soxhlet when used for DDT measurement, and equivalent to Soxhlet for BHCs. With ASE, organochlorine pesticide residues were detected in wastewater irrigated and non-wastewater irrigated soils from Tianjin. alpha-BHC, beta-BHC, delta-BHC, gamma-BHC, p,p'-DDE, p,p'-DDD, p,p'-DDT, o,p'-DDT ranged from 7.5 to 71.1 ng/g in wastewater irrigated vegetable and maize field and from 3.0 to 16.5 ng/g in wastewater irrigated paddy field. The eight pesticide residues from non-wastewater irrigated vegetable and maize field was in a range of 3.1-17.6 ng/g.