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基于三维荧光光谱特征峰的水体有机污染物综合指标检测
引用本文:严赟,杜树新,吴元清.基于三维荧光光谱特征峰的水体有机污染物综合指标检测[J].环境工程学报,2011,5(3):519-522.
作者姓名:严赟  杜树新  吴元清
作者单位:浙江大学工业控制技术国家重点实验室,浙江大学工业控制研究所,杭州310027
基金项目:国家“863”高技术研究发展计划项目(2009AA04Z123)
摘    要:对来源不同一的32个水样进行三维荧光光谱的测定,并用5种典型有机物的荧光特征峰A(腐殖酸类)、C(腐殖酸类)、B(络氨酸类)、T1(色氨酸类)、T2(色氨酸类)进行了单一和组合式建模,发现对于来源不同一的水体的总有机含碳量(TOC)、化学耗氧量(COD)的检测采用这种提取特征峰建模的效果并不理想.该研究说明,依据典型特...

关 键 词:三维荧光光谱  总有机含碳量  化学耗氧量  特征峰
修稿时间:3/3/2010 12:00:00 AM

Detection of dissolved organic matter in water based on characteristic peaks of 3D fluorescence spectra
Yan Yun,Du Shuxin and Wu Yuanqing.Detection of dissolved organic matter in water based on characteristic peaks of 3D fluorescence spectra[J].Techniques and Equipment for Environmental Pollution Control,2011,5(3):519-522.
Authors:Yan Yun  Du Shuxin and Wu Yuanqing
Institution:State Key Laboratory of Industrial Control Technology, Institute of Industrial Process Control, Zhejiang University, Hangzhou 310027, China,State Key Laboratory of Industrial Control Technology, Institute of Industrial Process Control, Zhejiang University, Hangzhou 310027, China and State Key Laboratory of Industrial Control Technology, Institute of Industrial Process Control, Zhejiang University, Hangzhou 310027, China
Abstract:Modelling for detecting dissolved organic matter with 32 water samples is addressed, using several typical organic characteristic peaks of 3D fluorescence spectra such as Peak A (humic-like), Peak C (humic-like), Peak B (tyrosine-like), Peak T1 (tryptophan-like) and Peak T2 (tryptophan-like). Experiments show that the modeling method is not satisfactory to detection of TOC and COD in water from different sources. It is concluded that the modeling method for detecting dissolved organic matters, based on the typical characteristic peaks of 3D fluorescence, is not universal for the variant water.
Keywords:3-D fluorescence spectra  total organic carbon  chemical oxygen demand  characteristic peak
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