首页 | 本学科首页   官方微博 | 高级检索  
     

煤氧化-热解进程的增失重阶段与动力学三因子分析
引用本文:贾海林1,杜志峰2,王健1,解俊杰1. 煤氧化-热解进程的增失重阶段与动力学三因子分析[J]. 中国安全生产科学技术, 2015, 11(8): 112-118. DOI: 10.11731/j.issn.1673-193x.2015.08.019
作者姓名:贾海林1  杜志峰2  王健1  解俊杰1
作者单位:(1. 河南理工大学 安全科学与工程学院,河南 焦作454000;2. 山西焦煤集团山西华晋吉宁煤业有限责任公司 吉宁煤矿, 山西 临汾042100)
摘    要:为分析煤氧化-热解进程的增失重阶段与动力学三因子,根据同一氧体积分数、5种不同升温速率下煤氧化-热解的TG-DTG曲线,探讨了煤氧化-热解进程经历的增失重阶段,基于Popescu法计算了不同阶段的动力学三因子。结果表明实验煤样的氧化-热解进程可分为失水失重、氧化增重、燃烧失重和燃尽恒重4个阶段。失水失重、氧化增重和燃烧失重阶段的反应机理分别为Mample单行法则、三维扩散模型和相边界反应的收缩球体模型;活化能分别为54.128 kJ·mol-1、152.252 kJ·mol-1和134.458 kJ·mol-1;指前因子的自然对数分别为16.832 s-1、32.597 s-1和18.365 s-1。

关 键 词:氧化-热解进程  增失重阶段  Popescu法  反应机理函数  动力学参数

Analysis on the weight increment and weight loss stage and the kinetic triplet during the oxidation-pyrolysis process of coal
JIA Hai-lin1,DU Zhi-feng2,WANG Jian1,JIE Jun-jie1. Analysis on the weight increment and weight loss stage and the kinetic triplet during the oxidation-pyrolysis process of coal[J]. Journal of Safety Science and Technology, 2015, 11(8): 112-118. DOI: 10.11731/j.issn.1673-193x.2015.08.019
Authors:JIA Hai-lin1  DU Zhi-feng2  WANG Jian1  JIE Jun-jie1
Affiliation:(1. School of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo Henan 454000, China;2. Jining Coal Mine, Jining Coal Industry Co., Ltd of Shanxi Coking Coal Group, Linfen Shanxi 042100, China)
Abstract:In order to analysis the weight increment and weight loss stage and the kinetic triplet during the oxidation-pyrolysis process of coal, based on the TG-DTG curves of coal oxidation-pyrolysis under the same oxygen volume fraction and five different heating rates, the weight increment and weight loss stage in the oxidation-pyrolysis process of coal was studied, and the kinetic triplet were calculated by the Popescu method. The result showed that the oxidation-pyrolysis process of coal sample can be separated into four stages which are respectively the weight loss stage by water loss, the weight increment stage by oxidation, the weight loss stage by combustion and the constant weight stage after burnout. The reaction mechanisms of the first three stages are respectively the single line law of Mample, the three dimensional diffusion model and the shrink sphere model of phase boundary reaction. The activation energies are respectively 54.128 kJ·mol-1, 152.252 kJ·mol-1 and 134.458 kJ·mol-1, and the natural logarithm of the pre-exponential factors are respectively 16.832 s-1, 32.597 s-1 and 18.365 s-1.
Keywords:oxidation-pyrolysis process  weight increment and weight loss stage  Popescu method  reaction mechanism function  kinetic parameters
本文献已被 CNKI 等数据库收录!
点击此处可从《中国安全生产科学技术》浏览原始摘要信息
点击此处可从《中国安全生产科学技术》下载免费的PDF全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号