| 超高交联吸附树脂对有机物质甲苯的吸附热力学研究 |
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| 引用本文： | 王京平,费正皓,唐树和,王莉莉.超高交联吸附树脂对有机物质甲苯的吸附热力学研究[J].环境工程学报,2006,7(11):49-53. |
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| 作者姓名： | 王京平 费正皓 唐树和 王莉莉 |
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| 作者单位： | 盐城师范学院江苏省滩涂生物资源与环境保护重点建设实验室,盐城,224002;盐城师范学院应用化学与环境工程研究所,盐城,224002;盐城师范学院江苏省滩涂生物资源与环境保护重点建设实验室,盐城,224002;盐城师范学院应用化学与环境工程研究所,盐城,224002 |
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| 基金项目： | 江苏省教育厅自然科学基金
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江苏省滩涂生物资源与环境保护重点建设实验室基金 |
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| 摘 要： | 比较了2种超高交联聚苯乙烯吸附树脂NDa99与ZH-04对甲苯的静态吸附行为.结果表明,在288～293 K和研究的浓度范围内,ZH-04、NDa99对甲苯的吸附平衡数据符合Freundlich和Langmuir吸附等温方程.吸附为放热过程,适当降低温度有利于吸附,并计算了甲苯在ZH-04和NDa99树脂上的吸附焓变、自由能变和熵变,对吸附行为进行了合理的解释,为废水处理提供一定的理论依据.
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| 关 键 词： | 超高交联吸附树脂 吸附热力学 甲苯 |
| 文章编号： | 1008-9241(2006)11-0049-05 |
| 修稿时间： | 2005年12月7日 |
The adsorption thermodynamics of toluene onto new hypercrosslinked polymeric resins |
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| Wang Jingping,Fei Zhenghao,Tang Shuhe,Wang Lili.The adsorption thermodynamics of toluene onto new hypercrosslinked polymeric resins[J].Techniques and Equipment for Environmental Pollution Control,2006,7(11):49-53. |
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| Authors: | Wang Jingping Fei Zhenghao Tang Shuhe Wang Lili |
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| Abstract: | A comparison of adsorption properties of the hypercrosslinked polymeric resins ZH-04 And NDa99 for the toluene was made,including the static equilibrium adsorption isotherms and the adsorption thermodynamic properties.Within temperature range of 288~293 K and investigative concentration range,equilibrium data for the adsorption of toluene from aqueous solutions by ZH-04 And NDa99 adsorbents had been obtained and were correlated with Freundlich and Langmuir equation.The results showed that the process of adsaorption of toluene from aqueous solution by ZH-04 And NDa99 is an exothermic process.Estimations of the isosteric enthalpy change of adsorption,free energy change and entropy change of adsorption are reported,and the adsorption behaviors are reasonable interpreted.Result of macroporous resins in the removal of toluene in aqueous solution is helpful to the further research of wasterwater application. |
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| Keywords: | hypercrosslinked polymeric resin adsorption thermodynamics toluene |
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