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TiO2膜降解水中污染物的稳定性考察与再生方法研究
引用本文:仇雁翎,李田,赵建夫,朱志良.TiO2膜降解水中污染物的稳定性考察与再生方法研究[J].环境工程学报,2007,1(11):23-28.
作者姓名:仇雁翎  李田  赵建夫  朱志良
作者单位:同济大学环境科学与工程学院长江水环境教育部重点实验室,上海 200092,同济大学环境科学与工程学院污染控制与资源化研究国家重点实验室,上海 200092,同济大学环境科学与工程学院污染控制与资源化研究国家重点实验室,上海 200092,同济大学环境科学与工程学院污染控制与资源化研究国家重点实验室,上海 200092
基金项目:国家“863”高技术研究发展计划资助项目(2002AA601250)
摘    要:针对实际水处理中对催化剂性能的要求,以光催化降解苯酚溶液作为探针反应,考察了玻璃纤维网上负载的TiO2膜催化剂长期使用条件下的稳定性,研究了催化剂在自来水中使用失活后的再生方法。结果表明,经过50次使用之后,膜催化剂120 min反应对苯酚的降解率从100%下降至83%,总体上看,所制催化剂还是具有相当好的稳定性;在反应器中用蒸馏水浸泡配合光催化反应对TiO2膜催化剂进行原位再生是一种可行的再生途径。

关 键 词:TiO2  稳定性  再生  玻璃纤维网  溶胶凝胶法
文章编号:1673-9108(2007)11-0023-06
修稿时间:2007-05-23

Study on stability and regeneration of TiO2 film used to remove pollutants in water
Qiu Yanling,Li Tian,Zhao Jianfu and Zhu Zhiliang.Study on stability and regeneration of TiO2 film used to remove pollutants in water[J].Techniques and Equipment for Environmental Pollution Control,2007,1(11):23-28.
Authors:Qiu Yanling  Li Tian  Zhao Jianfu and Zhu Zhiliang
Institution:Key Laboratory of Yangtze River Water Environment, Ministry of Education, College of Environmental Science and Engineering,Tongji University, Shanghai 200092,State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering,Tongji University, Shanghai 200092,State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering,Tongji University, Shanghai 200092 and State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering,Tongji University, Shanghai 200092
Abstract:The requirement to catalyst in practical water treatment was focused on in this study. Stability of TiO2 film fixed on fiber glass net after long term use was investigated by using photocatalytic degradation of phenol as probe reaction. Regeneration methods of TiO2 film after deactivation in tap water was also studied. It is showed that after being used for 50 times, the phenol removal rate decreases from 100% to 83% at 120 min of photocatalytic reaction. Nevertheless, the overall stability of the TiO2 catalyst made in this work is still acceptable. It is a feasible way to regenerate the TiO2 catalyst through soaking and UV photoreaction in distilled water.
Keywords:TiO2 film  stability  regeneration  fiber glass net  sol-gel method
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